bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Base Information

Chemical Name:bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium
CAS No.:22470-07-1
Molecular Formula:C₃₉H₃₆NP₂RhS₂
Molecular Weight:747.707
Hs Code.:

Synonyms:bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Suppliers and Price of bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Chemical Property:

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Technology Process of bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

There total 3 articles about bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 128-04-1
sodium dimethyldithiocarbamate

: 22470-07-1
bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Guidance literature:: In acetone; shaking, depositing on addn. of light petroleum; chromy. with C6H6/CH2Cl2, recrystn. from C6H6/petroleum;
DOI:10.1039/J19690000084

Reference yield:

: Rh(bis(triphenylphosphine))(O₂)(dimethyldithiocarbamato)

: 22470-07-1
bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Guidance literature:: In dichloromethane; excess PPh3, recrystn. from benzene/hexane;

Reference yield:

: Rh(bis(triphenylphosphine))(CO₃)(dimethyldithiocarbamato)*CH₂Cl₂

: 22470-07-1
bis(triphenylphosphine)(dimethyldithiocarbamato)rhodium

Guidance literature:: In dichloromethane-d2; excess triphenylphosphine, heated for prolonged time; isolation of CO2 adduct of bis(triphenylphosphine)(dithiocarbamato)rhodium unsuccessful, but characterization by NMR spectroscopy; ratio product/CO2 adduct about 5/1;;