Sodium dimethyldithiocarbamate

Base Information

• Chemical Name: Sodium dimethyldithiocarbamate
• CAS No.: 128-04-1
• Molecular Formula: C3H7NNaS2
• Molecular Weight: 179.24
• Hs Code.: 29302000
• Mol file: 128-04-1.mol

Synonyms:(Dimethyldithiocarbamato)sodium;Dimethyldithiocarbamicacid sodium salt;N,N-Dimethyldithiocarbamic acid sodium salt;

Chemical Property of Sodium dimethyldithiocarbamate

Chemical Property:

• Appearance/Colour: clear yellow liquid
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 120-122 °C (dec.)(lit.)
• Boiling Point: 129.4 °C at 760 mmHg
• Flash Point: 32 °C
• PSA: 60.63000
• Density: 1.17 g/cm³
• LogP: 1.03040
• Storage Temp.: 0-6°C
• Solubility.: Soluble in water
• Water Solubility.: 374g/L at 20℃

Purity/Quality:

95%min; 40%min ^*data from raw suppliers

DimethyldithiocarbamicAcidSodiumSalt ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,N
• Statements: 22-36-50
• Safety Statements: 26-36-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Description: Dithiocarbamates (DCs) are a well-known group of pesticides which have been used to control a number of species belonging to taxonomically different groups, e.g., bacteria, fungi, nematodes, and molluscs for over 60 years. The first integrated product containing sodium dimethyldithiocarbamate (SDMC) was registered in 1949.
• Uses: Sodium dimethyldithiocarbamate(SDMC) is used as a disinfectant, corrosion inhibitor, coagulant, vulcanizing agent, chelating agent, and fungicide. SDMC is used in water treatment, the rubber industry, and is a registered biocide for cutting oils and aqueous systems in industries such as leather tanning and paper manufacturing. It is also used as an antimicrobial agent in paints. generally SDMC are able to function as metal chelators and have been used in metal finishing operations and wastewater treatments to enhance the precipitation of metals. As a free radical inhibitor, it has been used in the rubber industry to rapidly stop the polymerization of synthesis. It is also used as a biocide for cutting oils and aqueous systems such as leather tanning and paper manufacturing.

Technology Process of Sodium dimethyldithiocarbamate

There total 6 articles about Sodium dimethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

carbon disulfide (75-15-0,12122-00-8) + N,N-dimethylammonium chloride (506-59-2) → sodium dimethyldithiocarbamate (128-04-1)

Guidance literature:

With sodium hydroxide; In methanol; for 3h; Ambient temperature;

DOI:10.1055/s-1996-4360

Reference yield: 99.85%

carbon disulfide (75-15-0,12122-00-8) + dimethyl amine (124-40-3) → sodium dimethyldithiocarbamate (128-04-1)

Guidance literature:

With sodium hydroxide; at 25 ℃; Temperature;

Reference yield:

Thiram (137-26-8,93196-73-7) → sodium dimethyldithiocarbamate (128-04-1)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; for 2h;

DOI:10.1039/DT9840002747

upstream raw materials:

Thiram

carbon disulfide

dimethyl amine

N,N-dimethylammonium chloride

Downstream raw materials:

dimethyl-dithiocarbamic acid-(2-chloro-allyl ester)

dimethyl-dithiocarbamic acid-[3-(4-chloro-phenoxy)-propyl ester]

dimethyl-dithiocarbamic acid-[4-(4-chloro-phenoxy)-butyl ester]

β,β--propionsaeure

Refernces

• 1、 Kamble, Atulkumar,Kamble, Ravindra,Dodamani, Suneel,Jalalpure, Sunil,Rasal, Vijaykumar,Kumbar, Mahadev,Joshi, Shrinivas,Dixit, Sheshagiri. "Design, synthesis and pharmacological analysis of 5-[4′-(substituted-methyl)[1,1′-biphenyl]-2-yl]-1H-tetrazoles". . p. 444 - 457. Retrieved 2017.
• 2、 Ramalingam,Ilakkiya. "Thiuram disulfide intercalated hybrid materials of layered lead and cadmium iodides". . p. 734 - 739. Retrieved 2016.
• 3、 Gueguen,Boisde,Queffelec,Haelters,Thouvenot,Corbel,Nodet. "Hapten synthesis for the development of a competitive inhibition enzyme-immunoassay for thiram". . p. 4492 - 4499. Retrieved 2000.
• 4、 -. "Method for continuously preparing sodium dimethyl dithio carbamate by micro-reaction device". Paragraph 0019-0021; 0022; 0023-0028. . Retrieved 2017/08/31.