N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine

Base Information

• Chemical Name: N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine
• CAS No.: 131189-16-7
• Molecular Formula: C₂₇H₂₂N₂O₂
• Molecular Weight: 406.484
• Mol file: 131189-16-7.mol

Synonyms:N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine

Chemical Property of N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine

There total 2 articles about N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4,4'-[methylenebis(oxy)]bis benzaldehyde (77354-99-5) + aniline (62-53-3) → N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (131189-16-7)

Guidance literature:

In benzene; for 1h; Heating; Dean-Stark trap;

DOI:10.1055/s-1990-27039

Reference yield:

4-hydroxy-benzaldehyde (123-08-0,65581-83-1) → N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (131189-16-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) aq. KOH / 1) benzene, refluxe, Dean-Stark trap, 1 h, 2) DMF, 80 deg C, 2 h

2: 94 percent / benzene / 1 h / Heating; Dean-Stark trap

With potassium hydroxide; In benzene;

DOI:10.1055/s-1990-27039

Reference yield: 14.0%

(benzyloxy)benzene (946-80-5) + N-(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (131189-16-7) → N,N,N',N'-Tetraphenyl-4-(methylenedioxy)bis(benzenemethanamine) (135505-56-5)

Guidance literature:

With sodium; N,N-dimethyl-formamide; at 100 ℃; for 1h;

DOI:10.1021/jo00020a032

upstream raw materials:

4,4'-[methylenebis(oxy)]bis benzaldehyde

aniline

4-hydroxy-benzaldehyde

Downstream raw materials:

N,N,N',N'-Tetraphenyl-4-(methylenedioxy)bis(benzenemethanamine)

C₃₅H₃₂O₄