BENZYL PHENYL ETHER

Base Information

• Chemical Name: BENZYL PHENYL ETHER
• CAS No.: 946-80-5
• Molecular Formula: C13H12O
• Molecular Weight: 184.238
• Hs Code.: 29093090
• Mol file: 946-80-5.mol

Synonyms:Ether,benzyl phenyl (6CI,7CI,8CI);Anisole, a-phenyl-;Benzyl phenyl ether;Benzyloxybenzene;NSC77971;Phenyl benzyl ether;(Benzyloxy)benzene;Anisole, α-phenyl-;Benzene, (phenoxymethyl)-;Benzyl phenyl ether;

Chemical Property of BENZYL PHENYL ETHER

Chemical Property:

• Appearance/Colour: Light brown-orange chunks
• Vapor Pressure: 0.00437mmHg at 25°C
• Melting Point: 39-41 °C(lit.)
• Refractive Index: 1.573
• Boiling Point: 287.1 °C at 760 mmHg
• Flash Point: 110.8 °C
• PSA: 9.23000
• Density: 1.057 g/cm³
• LogP: 3.26560
• Storage Temp.: 2-8°C
• Water Solubility.: Insoluble in water.

Purity/Quality:

98% ^*data from raw suppliers

Benzyl phenyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Benzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.

Technology Process of BENZYL PHENYL ETHER

There total 185 articles about BENZYL PHENYL ETHER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

benzyl chloride (100-44-7) + phenol (108-95-2,27073-41-2) → (benzyloxy)benzene (946-80-5) + o-Benzylphenol (28994-41-4)

Guidance literature:

With 1-butyl-3-methylimidazolium hydroxide; at 70 ℃; for 2h;

DOI:10.1007/s00706-006-0562-5

Reference yield: 52.0%

benzyl bromide (100-39-0) + phenol (108-95-2,27073-41-2) → p-benzylphenol (101-53-1) + (benzyloxy)benzene (946-80-5) + o-Benzylphenol (28994-41-4) + 2,6-dibenzylphenol (47157-01-7)

Guidance literature:

phenol; With n-butyllithium; In toluene; for 0.25h; Inert atmosphere;

benzyl bromide; In toluene; at 90 ℃; Temperature; Inert atmosphere;

DOI:10.1016/j.tet.2021.131935

Reference yield: 46.0%

benzyl bromide (100-39-0) + phenol (108-95-2,27073-41-2) → p-benzylphenol (101-53-1) + (benzyloxy)benzene (946-80-5) + o-Benzylphenol (28994-41-4)

Guidance literature:

phenol; With lithium hydroxide; In water; for 0.25h; Cooling with ice;

benzyl bromide; In water; at 20 ℃; Cooling with ice;

DOI:10.1016/j.tet.2021.131935

upstream raw materials:

benzoic acid phenyl ester

(chloromethoxy)benzene

benzyl tosylate

sodium phenoxide

Downstream raw materials:

p-benzylphenol

2-benzylquinoline

2-quinolin-2-yl-phenol

o-Benzylphenol

Refernces

• 1、 Lopu?anskaja, Eleana,Kooli, Anni,Paju, Anne,J?rving, Ivar,Lopp, Margus. "Towards ortho-selective electrophilic substitution/addition to phenolates in anhydrous solvents". . . Retrieved 2021/02/16.
• 2、 Huang, Binbin,Guo, Lin,Xia, Wujiong. "A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions". supporting information. p. 2095 - 2103. Retrieved 2021/03/26.