(1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene

Base Information

Chemical Name:(1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene
CAS No.:73538-58-6
Molecular Formula:
Molecular Weight:0
Hs Code.:
Mol file:73538-58-6.mol

Synonyms:

Suppliers and Price of (1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene

There total 19 articles about (1R,6S,7S)-3,7-Dimethyl-7-(4-methyl-3-pentenyl)bicyclo[4.1.0]hept-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130921-37-8,130921-38-9
(1R,6S,7S)-3-Iodo-7-(4-iodo-4-methyl-pentyl)-3,7-dimethyl-bicyclo[4.1.0]heptane

: 73538-58-6,89103-94-6,97948-75-9
Isosesquicarene

: 20479-23-6,23957-85-9,24406-01-7
episesquicarene

Guidance literature:: With 2,6-dimethylpyridine; tetrabutyl-ammonium chloride; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0040-4039(00)97558-0

Reference yield:

: 4096-34-8
cyclohex-3-enone

: 73538-58-6,89103-94-6,97948-75-9
Isosesquicarene

Guidance literature:: Multi-step reaction with 9 steps

1: 50 percent / CH₂Cl₂ / 15 °C / Irradiation

2: 74 percent / HC(OMe)3, TsOH

3: 1) MeLi / 1) -78 deg C 2) -30 to 20 deg C

4: 66 percent / mCPBA / CHCl₃ / 20 °C

5: 85 percent / H₂ / Raney Ni / tetrahydrofuran / 0 °C

6: 100 percent / H₂SO₄, SiO₂

7: diethyl ether / -78 to 20 deg C

8: (PhO)3PCH₃I

9: Bu₄NCl, 2,6-lutidine

With 2,6-dimethylpyridine; sulfuric acid; tetrabutyl-ammonium chloride; methyltriphenoxyphosphonium iodide; methyllithium; hydrogen; silica gel; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; trimethyl orthoformate; nickel; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)97558-0

Reference yield:

: 86958-30-7
5-Bromoethynyl-3,3-dimethyl-3H-pyrazole

: 73538-58-6,89103-94-6,97948-75-9
Isosesquicarene

Guidance literature:: Multi-step reaction with 9 steps

1: 50 percent / CH₂Cl₂ / 15 °C / Irradiation

2: 74 percent / HC(OMe)3, TsOH

3: 1) MeLi / 1) -78 deg C 2) -30 to 20 deg C

4: 66 percent / mCPBA / CHCl₃ / 20 °C

5: 85 percent / H₂ / Raney Ni / tetrahydrofuran / 0 °C

6: 100 percent / H₂SO₄, SiO₂

7: diethyl ether / -78 to 20 deg C

8: (PhO)3PCH₃I

9: Bu₄NCl, 2,6-lutidine

With 2,6-dimethylpyridine; sulfuric acid; tetrabutyl-ammonium chloride; methyltriphenoxyphosphonium iodide; methyllithium; hydrogen; silica gel; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; trimethyl orthoformate; nickel; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)97558-0