7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

Base Information

Chemical Name:7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine
CAS No.:129056-02-6
Molecular Formula:C₃₇H₄₁NO₇S
Molecular Weight:643.801
Hs Code.:

Synonyms:7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

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Chemical Property of 7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

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Technology Process of 7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

There total 3 articles about 7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116438-11-0
6,9-dimethyl-7,10-dioxo-5,5-(ethylenedioxy)-8-methoxy-1-(p-tolylsulfonyl)-1,2,3,4,5,6,7,10-octahydro-1-benzazocine

: 129056-02-6
7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: Multi-step reaction with 2 steps

1: Na₂S₂O₄, n-Bu₄NHSO₄ / CH₂Cl₂ / 0.5 h / Ambient temperature

2: K₂CO₃, 18-crown-6 / tetrahydrofuran / 19 h / Heating

With sodium dithionite; 18-crown-6 ether; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; In tetrahydrofuran; dichloromethane;

Reference yield:

: 100-39-0
benzyl bromide

: C₂₃H₂₉NO₇S

: 129056-02-6
7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: With 18-crown-6 ether; potassium carbonate; In tetrahydrofuran; for 19h; Yield given; Heating;

Reference yield:

: 116438-11-0
6,9-dimethyl-7,10-dioxo-5,5-(ethylenedioxy)-8-methoxy-1-(p-tolylsulfonyl)-1,2,3,4,5,6,7,10-octahydro-1-benzazocine

: 100-39-0
benzyl bromide

: 129056-02-6
7,10-dibenzoyloxy-5,5-ethylenedioxy-8-methoxy-6,9-dimethyl-1-p-toluenesulfonyl-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: With sodium dithionite; potassium carbonate; 18-crown-6 ether; tetra(n-butyl)ammonium hydrogensulfate; Yield given. Multistep reaction; 1.) H₂O, CH₂Cl₂, room temperature, 2.) THF, reflux, 19 h;
DOI:10.1039/c39900000468