(2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol

Base Information

Chemical Name:(2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol
CAS No.:100296-57-9
Molecular Formula:C₁₄H₂₀O₃
Molecular Weight:236.311
Hs Code.:

Synonyms:(2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol

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Chemical Property of (2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol

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Technology Process of (2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol

There total 4 articles about (2R,3R)-4-(benzyloxy)-2-isopropenyl-1,3-butanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2568-24-3
2-phenyl-4,7-dihydro-1,3-dioxepine

: 87116-66-3,100296-57-9
(2S,3R)-4-Benzyloxy-2-isopropenyl-butane-1,3-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / aluminium chloride, lithium aluminium hydride / diethyl ether / 1) 0 deg C, 30 min, 2) r.t., 30 min

2: 84 percent / t-butyl hydroperoxide / vanadyl acetoacetate / CH₂Cl₂; toluene / 96 h / Ambient temperature

3: 1) n-BuLi, LiCl, 2) LiCl / THF, 1a) -78 deg C, 5 min, 1b) 0 deg C, 10 min, 2) 25 deg C, 14 h

With tert.-butylhydroperoxide; lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; lithium chloride; vanadyl acetoacetonate; In diethyl ether; dichloromethane; toluene;

Reference yield:

: 81028-03-7
(Z)-4-benzyloxy-but-2-en-1-ol

: 87116-66-3,100296-57-9
(2S,3R)-4-Benzyloxy-2-isopropenyl-butane-1,3-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / t-butyl hydroperoxide / vanadyl acetoacetate / CH₂Cl₂; toluene / 96 h / Ambient temperature

2: 1) n-BuLi, LiCl, 2) LiCl / THF, 1a) -78 deg C, 5 min, 1b) 0 deg C, 10 min, 2) 25 deg C, 14 h

With tert.-butylhydroperoxide; n-butyllithium; lithium chloride; vanadyl acetoacetonate; In dichloromethane; toluene;

Reference yield:

: 100-52-7
benzaldehyde

: 87116-66-3,100296-57-9
(2S,3R)-4-Benzyloxy-2-isopropenyl-butane-1,3-diol

Guidance literature:: Multi-step reaction with 4 steps

1: toluene-p-sulfonic acid / benzene / 3.5 h / Heating

2: 77 percent / aluminium chloride, lithium aluminium hydride / diethyl ether / 1) 0 deg C, 30 min, 2) r.t., 30 min

3: 84 percent / t-butyl hydroperoxide / vanadyl acetoacetate / CH₂Cl₂; toluene / 96 h / Ambient temperature

4: 1) n-BuLi, LiCl, 2) LiCl / THF, 1a) -78 deg C, 5 min, 1b) 0 deg C, 10 min, 2) 25 deg C, 14 h

With tert.-butylhydroperoxide; lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; toluene-4-sulfonic acid; lithium chloride; vanadyl acetoacetonate; In diethyl ether; dichloromethane; toluene; benzene;