3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

Base Information

Chemical Name:3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol
CAS No.:212781-52-7
Molecular Formula:C₄₉H₉₂O₆
Molecular Weight:777.266
Hs Code.:

Synonyms:3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

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Chemical Property of 3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

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Technology Process of 3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

There total 17 articles about 3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 100-39-0
benzyl bromide

: 212781-49-2
3,3'-O-(1,16-hexadecamethylene)bis<2-O-(R)-3,7-dimethyloctyl-sn-glycerol>

: 212781-52-7
3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

: 222984-15-8
3,3'-O-(1,16-hexadecamethylene)bis<1-O-benzyl-2-O-<(R)-3,7-dimethyloctyl>-sn-glycerol>

Guidance literature:: With silver(l) oxide; In dichloromethane;
DOI:10.1039/a802338g

Reference yield:

: 10340-84-8
(R)-8-bromo-2,6-dimethyloct-2-ene

: 212781-52-7
3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / NaH / tetrahydrofuran / 3 h / 120 °C

2: 90 percent / H₂, Et₃N / Pd/C / ethyl acetate / 8 h / Ambient temperature

3: 75 percent / HCO₂H / diethyl ether / 0.75 h / Ambient temperature

4: 50 percent / Ag₂O / CH₂Cl₂ / 3 h / Heating

With formic acid; hydrogen; sodium hydride; triethylamine; silver(l) oxide; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1021/jo9822028

Reference yield:

: 7735-42-4
1,16-hexadecanediol

: 212781-52-7
3,3'-O-(1,16-hexadecamethylene)-2,2'-O-<(R)-3,7-dimethyloctyl>-1'-O-benzyl-sn-diglycerol

Guidance literature:: Multi-step reaction with 8 steps

1: 80 percent / 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

2: 83 percent / PS / CH₂Cl₂ / 15 h / Heating

3: 93 percent / Dowex H⁺ resin / methanol / 20 h / Heating

4: 80 percent / Et₃N, DMAP / tetrahydrofuran / 4 h / Heating

5: 80 percent / NaH / tetrahydrofuran / 3 h / 120 °C

6: 90 percent / H₂, Et₃N / Pd/C / ethyl acetate / 8 h / Ambient temperature

7: 75 percent / HCO₂H / diethyl ether / 0.75 h / Ambient temperature

8: 50 percent / Ag₂O / CH₂Cl₂ / 3 h / Heating

With 2,6-dimethylpyridine; dmap; formic acid; Dowex H⁺ resin; hydrogen; sodium hydride; triethylamine; silver(l) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1021/jo9822028