[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

Base Information

Chemical Name:[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane
CAS No.:310889-27-1
Molecular Formula:C₃₀H₃₆O₂Si
Molecular Weight:456.7
Hs Code.:

[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-<i>tert</i>-butyl-diphenyl-silane

Synonyms:[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

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Chemical Property of [2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

Chemical Property:

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Technology Process of [2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

There total 4 articles about [2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 131186-52-2
(((benzyloxy)methyl)sulfonyl)benzene

: 310889-26-0
2-(tert-butyl-diphenyl-silanyloxymethyl)-3-methyl-but-2-enal

: 310889-27-1
[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: (((benzyloxy)methyl)sulfonyl)benzene; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃;

2-(tert-butyl-diphenyl-silanyloxymethyl)-3-methyl-but-2-enal; With benzoyl chloride; In tetrahydrofuran; at -78 - 20 ℃; for 0.916667h;

With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; samarium diiodide; In tetrahydrofuran; at 20 ℃; for 1h; Further stages.;
DOI:10.1039/b005533f

Reference yield:

: 2035-85-0
2-(Isopropylidene)-1,3-propanediol

: 310889-27-1
[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / tetrahydrofuran / 1 h / 20 °C

1.2: tetrahydrofuran / 15 h / 20 °C

2.1: TPAP; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 1 h / 20 °C

3.1: LDA / tetrahydrofuran / -78 °C

3.2: Benzoyl chloride / tetrahydrofuran / 0.92 h / -78 - 20 °C

3.3: SmI₂; DMPU / tetrahydrofuran / 1 h / 20 °C

With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; 1.1: Metallation / 1.2: Etherification / 2.1: Oxidation / 3.1: Metallation / 3.2: Substitution / 3.3: Oxidation;
DOI:10.1039/b005533f

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 310889-27-1
[2-(2-benzyloxy-vinyl)-3-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / tetrahydrofuran / 1 h / 20 °C

1.2: tetrahydrofuran / 15 h / 20 °C

2.1: TPAP; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 1 h / 20 °C

3.1: LDA / tetrahydrofuran / -78 °C

3.2: Benzoyl chloride / tetrahydrofuran / 0.92 h / -78 - 20 °C

3.3: SmI₂; DMPU / tetrahydrofuran / 1 h / 20 °C

With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; 1.1: Metallation / 1.2: Etherification / 2.1: Oxidation / 3.1: Metallation / 3.2: Substitution / 3.3: Oxidation;
DOI:10.1039/b005533f