1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

Base Information

Chemical Name:1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen
CAS No.:80971-10-4
Molecular Formula:C₂₁H₂₃N₃O₃
Molecular Weight:365.432
Hs Code.:

Synonyms:1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

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Chemical Property of 1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

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Technology Process of 1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

There total 9 articles about 1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 80971-12-6
Methanesulfonic acid (1R,4R,5S,6R)-5,6-bis-benzyloxy-4-methoxy-cyclohex-2-enyl ester

: 1L-(1N,2,4/3)-1-Azido-3,4-di-O-benzyl-2-O-methyl-2,3,4-trihydroxy-5-cyclohexen

: 80971-10-4
1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 0 ℃;

Reference yield:

: 642-38-6
quebrachitol

: 80971-10-4
1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

Guidance literature:: Multi-step reaction with 9 steps

1: 85 percent / anh. p-toluenesulfonic acid / dimethylformamide / 20 h / 80 °C

2: 96 percent / toluene; CHCl₃ / 60 °C

3: 99percent acetic acid / 2 h / 40 °C

4: 79 percent / NaH / dimethylformamide / 20 h / Ambient temperature

5: 94 percent / 95percent acetic acid / 10 h / 80 °C

6: 93 percent / 1N NaOCH₃ / methanol / 1 h

7: 87 percent / 3-methyl-2-selenoxobenzothiazol, trifluoro acetic acid / CH₂Cl₂ / Ambient temperature

8: pyridine; CHCl₃ / 0 °C

9: 67 percent / NaN₃ / dimethylformamide / 0 °C

With sodium azide; N-methyl-1,3-benzothiazole-2(3H)-selone; sodium methylate; sodium hydride; toluene-4-sulfonic acid; acetic acid; trifluoroacetic acid; In pyridine; methanol; dichloromethane; chloroform; N,N-dimethyl-formamide; toluene;

Reference yield:

: 100-39-0
benzyl bromide

: 80971-10-4
1D-(1N,2,4/3)-1-Azido-2,3-di-O-benzyl-4-O-methyl-2,3,4-trihydroxy-5-cyclohexen

Guidance literature:: Multi-step reaction with 6 steps

1: 79 percent / NaH / dimethylformamide / 20 h / Ambient temperature

2: 94 percent / 95percent acetic acid / 10 h / 80 °C

3: 93 percent / 1N NaOCH₃ / methanol / 1 h

4: 87 percent / 3-methyl-2-selenoxobenzothiazol, trifluoro acetic acid / CH₂Cl₂ / Ambient temperature

5: pyridine; CHCl₃ / 0 °C

6: 67 percent / NaN₃ / dimethylformamide / 0 °C

With sodium azide; N-methyl-1,3-benzothiazole-2(3H)-selone; sodium methylate; sodium hydride; acetic acid; trifluoroacetic acid; In pyridine; methanol; dichloromethane; chloroform; N,N-dimethyl-formamide;