Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester

Base Information

• Chemical Name: Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester
• CAS No.: 104688-95-1
• Molecular Formula: C₁₅H₁₃N₃OS₂
• Molecular Weight: 315.42
• Mol file: 104688-95-1.mol

Synonyms:Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester

Chemical Property of Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester

There total 2 articles about Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-chloroacetaminoazobenzene (19680-35-4) + methyl iodide (74-88-4) → Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester (104688-95-1)

Guidance literature:

With sulfur; triethylamine; Yield given. Multistep reaction; 1.) DMF, 2 h, 2.) 10 deg C;

Reference yield:

(1R,4S)-3-Methylsulfanyl-2-thia-bicyclo[2.2.1]hept-5-ene-3-carboxylic acid (4-phenylazo-phenyl)-amide (110968-47-3) → Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester (104688-95-1)

Guidance literature:

heating;

Reference yield: 100.0%

Oxo-(4-phenylazo-phenylamino)-dithioacetic acid methyl ester (104688-95-1) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (1R,4S)-3-Methylsulfanyl-2-thia-bicyclo[2.2.1]hept-5-ene-3-carboxylic acid (4-phenylazo-phenyl)-amide (110968-47-3)

Guidance literature:

In chloroform; Heating;

upstream raw materials:

(1R,4S)-3-Methylsulfanyl-2-thia-bicyclo[2.2.1]hept-5-ene-3-carboxylic acid (4-phenylazo-phenyl)-amide

4-chloroacetaminoazobenzene

methyl iodide

Downstream raw materials:

5-Methylsulfanyl-[1,3,4]thiadiazole-2-carboxylic acid (4-phenylazo-phenyl)-amide

C₁₅H₁₄N₆O₂S

2-(Cyanomethyl-amino)-N-(4-phenylazo-phenyl)-2-thioxo-acetamide

5'-Methylsulfanyl-[2,2']bi[[1,3,4]thiadiazolyl]-5-carboxylic acid (4-phenylazo-phenyl)-amide

Refernces

• 1、 Thiel, Wilfried,Mayer, Roland. "-Cycloadditionen mit 1,1-Dithio-oxalsaeureesteramiden". . p. 433 - 434. Retrieved 2007/10/02.