(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Base Information

Chemical Name:(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde
CAS No.:402559-34-6
Molecular Formula:C₁₇H₂₀O₅
Molecular Weight:304.343
Hs Code.:

Synonyms:(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

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Chemical Property of (3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

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Technology Process of (3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

There total 4 articles about (3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 402559-32-4
(2'E)-3-O-(3'-phenyl-2'-propenyl)-1,2-O-isopropylidene-α-D-glucofuranose

: 402559-34-6
(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: With sodium periodate; water; sodium hydrogencarbonate; In dichloromethane; at 0 - 20 ℃; for 5h;
DOI:10.1016/S0040-4039(01)01889-5

Reference yield:

: 4392-24-9
Cinnamyl bromide

: 402559-34-6
(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / NaH / dimethylformamide / 1 h / 0 - 20 °C

2: 89 percent / AcOH; water / 12 h / 20 °C

3: 91 percent / NaIO₄; NaHCO₃; water / CH₂Cl₂ / 5 h / 0 - 20 °C

With sodium periodate; water; sodium hydride; sodium hydrogencarbonate; acetic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(01)01889-5

Reference yield:

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 402559-34-6
(3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / NaH / dimethylformamide / 1 h / 0 - 20 °C

2: 89 percent / AcOH; water / 12 h / 20 °C

3: 91 percent / NaIO₄; NaHCO₃; water / CH₂Cl₂ / 5 h / 0 - 20 °C

With sodium periodate; water; sodium hydride; sodium hydrogencarbonate; acetic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(01)01889-5