2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Base Information

Chemical Name:2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran
CAS No.:413627-64-2
Molecular Formula:C₄₇H₆₅NO₆S
Molecular Weight:772.102
Hs Code.:

Synonyms:2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Suppliers and Price of 2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

There total 5 articles about 2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38622-91-2,36635-61-7
[(p-methylphenyl)sulfonylmethyl]isonitrile

: 413627-60-8
2-(6-bromo-2-methyl-2-p-tolylhexyloxy)-tetrahydropyran

: 413627-64-2
2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Guidance literature:: With tetra-(n-butyl)ammonium iodide; sodium hydride; In diethyl ether; dimethyl sulfoxide; at 20 ℃; for 24h;
DOI:10.1021/jm040006p

Reference yield:

: 14062-19-2
p-tolylacetic acid ethyl ester

: 413627-64-2
2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Guidance literature:: Multi-step reaction with 5 steps

1.1: LDA / tetrahydrofuran; heptane; ethylbenzene / 1 h / -40 °C

1.2: 86 percent / DMPU / tetrahydrofuran; heptane; ethylbenzene / -40 - 20 °C

2.1: LDA / tetrahydrofuran; heptane / 1 h / -78 °C

2.2: 90 percent / DMPU / tetrahydrofuran; heptane / -78 - 20 °C

3.1: LiBH₄; MeOH / CH₂Cl₂ / Heating

4.1: pTsOH*H₂O / CH₂Cl₂ / 20 °C

5.1: NaH; NBu₄I / dimethylsulfoxide; diethyl ether / 24 h / 20 °C

With methanol; lithium borohydride; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; n-heptane; dichloromethane; ethylbenzene; dimethyl sulfoxide;
DOI:10.1021/jm040006p

Reference yield:

: 78926-01-9
2-(4-methylphenyl)propanoic acid ethyl ester

: 413627-64-2
2-[7-isocyano-2,12-dimethyl-2, 12-di-p-tolyl-13-(tetrahydropyran-2-yloxy)-7-(toluene-4-sulfonyl)-tridecanyloxy]-tetrahydropyran

Guidance literature:: Multi-step reaction with 4 steps

1.1: LDA / tetrahydrofuran; heptane / 1 h / -78 °C

1.2: 90 percent / DMPU / tetrahydrofuran; heptane / -78 - 20 °C

2.1: LiBH₄; MeOH / CH₂Cl₂ / Heating

3.1: pTsOH*H₂O / CH₂Cl₂ / 20 °C

4.1: NaH; NBu₄I / dimethylsulfoxide; diethyl ether / 24 h / 20 °C

With methanol; lithium borohydride; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; n-heptane; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jm040006p