Technology Process of C48H74O7Si3
There total 6 articles about C48H74O7Si3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C39H64O3Si3;
With
9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran;
at 20 ℃;
for 5h;
Inert atmosphere;
With
potassium phosphate;
In
tetrahydrofuran;
Inert atmosphere;
methyl 2-bromo-6-hydroxy-4-methoxybenzoate;
With
trifuran-2-yl-phosphane; palladium diacetate;
In
tetrahydrofuran; 1,2-dimethoxyethane;
for 19h;
Inert atmosphere;
Reflux;
DOI:10.1021/ml1001807
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: water; toluene-4-sulfonic acid / tetrahydrofuran / 10 h / 20 °C / Inert atmosphere
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran / -78 - -10 °C / Inert atmosphere
3.2: -78 - 20 °C / Inert atmosphere
4.1: 1H-imidazole / N,N-dimethyl-formamide / 15 h / 20 °C / Inert atmosphere
5.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere
5.2: Inert atmosphere
5.3: 19 h / Inert atmosphere; Reflux
With
1H-imidazole; n-butyllithium; oxalyl dichloride; water; toluene-4-sulfonic acid; dimethyl sulfoxide; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
2.1: Swern oxidation / 2.2: Swern oxidation / 5.1: Suzuki Miyaura coupling / 5.2: Suzuki Miyaura coupling / 5.3: Suzuki Miyaura coupling;
DOI:10.1021/ml1001807
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 1H-imidazole / N,N-dimethyl-formamide / 15 h / 20 °C / Inert atmosphere
2.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere
2.2: Inert atmosphere
2.3: 19 h / Inert atmosphere; Reflux
With
1H-imidazole; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; N,N-dimethyl-formamide;
2.1: Suzuki Miyaura coupling / 2.2: Suzuki Miyaura coupling / 2.3: Suzuki Miyaura coupling;
DOI:10.1021/ml1001807
