3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Base Information

Chemical Name:3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol
CAS No.:470665-47-5
Molecular Formula:C₅₅H₈₂N₂O₈
Molecular Weight:899.265
Hs Code.:

Synonyms:3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Suppliers and Price of 3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

There total 4 articles about 3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 470665-45-3
3,4,6-tri-O-benzyl-1,5-N-[(O-tert-butyl-carboxymethyl)imino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

: 470665-47-5
3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Guidance literature:: With trifluoroacetic acid; at 20 ℃;
DOI:10.1081/CAR-120004331

Reference yield:

: 250737-19-0
3,4,6-tri-O-benzyl-2-[(benzyloxycarbonyl)amino]-1,2,5-trideoxy-1,5-imino-D-glucitol

: 470665-47-5
3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / Cs₂CO₃ / dimethylformamide / 16 h / 20 °C

2: 100 percent / H₂ / Pd/C / ethyl acetate / 1 h / 760 Torr

3: 70 percent / (i-Pr)2NEt; PyBOP / CH₂Cl₂

4: 83 percent / TFA / 20 °C

With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; hydrogen; caesium carbonate; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; palladium on activated charcoal; In dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1081/CAR-120004331

Reference yield:

: 470665-42-0
3,4,6-tri-O-benzyl-2-[(benzyloxycarbonyl)amino]-1,5-N-(O-tert-butyl-carboxymethyl)imino-1,2,5-trideoxy-D-glucitol

: 470665-47-5
3,4,6-tri-O-benzyl-1,5-N-[carboxymethylimino]-2-[(R)-3-(dodecanoyloxytetradecanoyl)]amino-1,2,5-trideoxy-D-glucitol

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / H₂ / Pd/C / ethyl acetate / 1 h / 760 Torr

2: 70 percent / (i-Pr)2NEt; PyBOP / CH₂Cl₂

3: 83 percent / TFA / 20 °C

With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; hydrogen; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; palladium on activated charcoal; In dichloromethane; ethyl acetate;
DOI:10.1081/CAR-120004331