methylsulfanylformyl chloride

Base Information

• Chemical Name: methylsulfanylformyl chloride
• CAS No.: 2812-72-8
• Molecular Formula: C2H3ClOS
• Molecular Weight: 110.564
• Mol file: 2812-72-8.mol

Synonyms:Thiokohlensaeure-chlorid-O-methylester;methyl chlorothioformate;O-methyl chlorothioformate;chlorothiocarbonic acid O-methyl ester;Chlorothiokohlensaeure-O-methylester;methyl chlorothionoformate;

Chemical Property of methylsulfanylformyl chloride

Chemical Property:

• Boiling Point: 107.6°Cat760mmHg
• Flash Point: 31.1°C
• PSA: 41.32000
• Density: 1.315g/cm³
• LogP: 1.15650

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methylsulfanylformyl chloride

There total 3 articles about methylsulfanylformyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(methoxydichloromethyl)(chlorocarbonyl)trisulfane (88766-42-1) + N-methylaniline (100-61-8) → methyl chlorothioformate (2812-72-8) + (methylphenylcarbamoyl)disulfanyl chloride (100244-49-3) + C10H11Cl2NO2S3 (100244-45-9)

Guidance literature:

In diethyl ether; at 5 ℃; for 0.0833333h; Yields of byproduct given;

DOI:10.1021/jo00360a039

Reference yield:

(methoxy(thiocarbonyl))sulfenyl chloride (124513-37-7) → methyl chlorothioformate (2812-72-8) + dimexano (1468-37-7)

Guidance literature:

In chloroform-d1; at 25 ℃; for 24h; Title compound not separated from byproducts;

DOI:10.1021/jo00292a018

Reference yield:

C10H11Cl2NO2S3 (100244-45-9) → methyl chlorothioformate (2812-72-8) + (methylphenylcarbamoyl)disulfanyl chloride (100244-49-3)

Guidance literature:

In chloroform-d1; for 0.166667h;

DOI:10.1021/jo00360a039

upstream raw materials:

(methoxy(thiocarbonyl))sulfenyl chloride

C₁₀H₁₁Cl₂NO₂S₃

(methoxydichloromethyl)(chlorocarbonyl)trisulfane

N-methylaniline

Downstream raw materials:

N,N',N'-Trimethyl-hydrazinecarbothioic acid O-methyl ester

Dimethyl monothionocarbonate

methylene chloride

methyl thiochloroformate

Refernces

• 1、 Schroll, Alayne L.,Barany, George. "Novel Symmetrical and Mixed Carbamoyl and Amino Polysulfanes by Reactions of (Alkoxydichloromethyl)polysulfanyl Substrates with N-Methylaniline". . p. 1866 - 1881. Retrieved 2007/10/02.