(η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese

Base Information

• Chemical Name: (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese
• CAS No.: 85320-15-6
• Molecular Formula: C₂₄H₂₀MnO₂P
• Molecular Weight: 426.333
• Mol file: 85320-15-6.mol

Synonyms:(η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese

Chemical Property of (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese

There total 2 articles about (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

cymantrene (12079-65-1) + cyclopentadien-5-yldiphenylphosphine (83334-39-8) → (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese (85320-15-6)

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); Mn complex photolysing in THF for 4 h at 15°C with stirring under Ar, adding to a freshly prepared phosphine soln., stirring overnight, evapg. with Al2O3, chromg. on Al2O3 column; purified by recrystn. from CH2Cl2/hexane at -20°C; identified byelem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a024

Reference yield: 39.0%

cymantrene (12079-65-1) + (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium (85320-12-3) → (η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium-P)manganese (85320-14-5) + (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese (85320-15-6)

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); Mn complex photolysing in THF for 4 h at 15°C with stirring under Ar, adding to Ti complex, stirring overnight, evapg. with Al2O3, chromg. on Al2O3 column; purified by recrystn. from CH2Cl2/hexane at -20°C; identified byelem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a024

upstream raw materials:

cymantrene

(η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

cyclopentadien-5-yldiphenylphosphine