(η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

Base Information

• Chemical Name: (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium
• CAS No.: 85320-12-3
• Molecular Formula: C₂₄H₁₉O₂PTi
• Molecular Weight: 418.267
• Mol file: 85320-12-3.mol

Synonyms:(η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

Chemical Property of (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

There total 1 articles about (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

(η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium (85320-11-2) → (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium (85320-12-3)

Guidance literature:

With Al; HgCl₂; CO; In tetrahydrofuran; Ti complex, Al turnings and HgCl2 in THF stirring overnight under Ar, CO passing over the soln.; color changing from red-brown to purple; filtering through Al2O3, evapg.; purified by dissolving in hexane/ether, filtering, evapg.; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a024

Reference yield: 39.0%

cymantrene (12079-65-1) + (η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium (85320-12-3) → (η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium-P)manganese (85320-14-5) + (η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese (85320-15-6)

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); Mn complex photolysing in THF for 4 h at 15°C with stirring under Ar, adding to Ti complex, stirring overnight, evapg. with Al2O3, chromg. on Al2O3 column; purified by recrystn. from CH2Cl2/hexane at -20°C; identified byelem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a024

upstream raw materials:

(η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium

Downstream raw materials:

(η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium-P)manganese

(η-5-cyclopentadienyl)dicarbony[(diphenylphosphino)cyclopentadiene-P]manganese