6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

Base Information

Chemical Name:6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde
CAS No.:165674-18-0
Molecular Formula:C₃₂H₄₃NO₁₀Si
Molecular Weight:629.78
Hs Code.:

6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo<d>-1,3-dioxolane-5-carbaldehyde

Synonyms:6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

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Chemical Property of 6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

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Technology Process of 6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

There total 12 articles about 6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 165674-17-9
(6-bromo-2H-benzo<3,4-d>-1,3-dioxolan-5-yl)methyl (2S,3R)-3-<(4S,5R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoate

: 165674-18-0
6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

Guidance literature:: With n-butyllithium; tetrapropylammonium perruthennate; Yield given. Multistep reaction;
DOI:10.1021/ja00132a047

Reference yield:

: 23843-32-5
2,3-Isopropylidene-D-gulono-γ-lactone

: 165674-18-0
6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

Guidance literature:: Multi-step reaction with 9 steps

1: imidazole

2: DIBAL / -78 °C

4: DIEA

5: HF, Py

6: TPAP, NMO

7: NaClO₂, KH₂PO₄

8: Ph₃P, DEAD

9: 1.) n-BuLi, 2.) TPAP

With pyridine; 1H-imidazole; sodium chlorite; potassium dihydrogenphosphate; n-butyllithium; N-methyl-2-indolinone; tetrapropylammonium perruthennate; hydrogen fluoride; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; triphenylphosphine; diethylazodicarboxylate;
DOI:10.1021/ja00132a047

Reference yield:

: 2687-43-6
O-benzylhydoxylamine hydrochloride

: 165674-18-0
6-((2S,3R)-3-<(5S,4R)-5-<(1Z)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-3-(methoxymethoxy)-2-(1,1,2,2-tetramethyl-1-silapropoxy)propanoyl)-2H-benzo-1,3-dioxolane-5-carbaldehyde

Guidance literature:: Multi-step reaction with 7 steps

2: DIEA

3: HF, Py

4: TPAP, NMO

5: NaClO₂, KH₂PO₄

6: Ph₃P, DEAD

7: 1.) n-BuLi, 2.) TPAP

With pyridine; sodium chlorite; potassium dihydrogenphosphate; n-butyllithium; N-methyl-2-indolinone; tetrapropylammonium perruthennate; hydrogen fluoride; N-ethyl-N,N-diisopropylamine; triphenylphosphine; diethylazodicarboxylate;
DOI:10.1021/ja00132a047