Technology Process of C25H33BrO5Si
There total 9 articles about C25H33BrO5Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
DOI:10.1039/a905631i
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 90 percent / DMAP; pyridine
2: 91 percent / MCPBA / CH2Cl2 / 20 °C
With
pyridine; dmap; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
1: Acylation / 2: Epoxidation;
DOI:10.1039/a905631i
-
-
194796-30-0
(+)-(1R,4S,4aR,5S,8aS)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 89 percent / NaH / tetrahydrofuran / 20 °C
2: 82 percent / O2; KF; (EtO)3P / dimethylsulfoxide
3: NaBH4 / methanol; tetrahydrofuran / -15 °C
4: NBS / CH2Cl2 / -15 °C
5: 84 percent / POCl3; pyridine / 50 °C
6: DIBAL-H / toluene / -78 °C
7: 90 percent / DMAP; pyridine
8: 91 percent / MCPBA / CH2Cl2 / 20 °C
With
pyridine; dmap; potassium fluoride; sodium tetrahydroborate; N-Bromosuccinimide; oxygen; sodium hydride; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; triethyl phosphite; trichlorophosphate;
In
tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; toluene;
1: Condensation / 2: Oxidation / 3: Reduction / 4: Bromination / 5: Dehydration / 6: Reduction / 7: Acylation / 8: Epoxidation;
DOI:10.1039/a905631i
