[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Base Information

Chemical Name:[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate
CAS No.:1176869-75-2
Molecular Formula:C₂₂H₂₂O₃SSi
Molecular Weight:394.566
Hs Code.:

Synonyms:[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Suppliers and Price of [5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

There total 3 articles about [5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 1176869-71-8
{5-[(4-methoxyphenyl)sulfinyl]-2-furyl}(trimethyl)silane

: 13984-49-1
(phenylethynyl)zinc chloride

: 1176869-75-2
[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Guidance literature:: {5-[(4-methoxyphenyl)sulfinyl]-2-furyl}(trimethyl)silane; With 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride complex; In tetrahydrofuran; at -40 ℃; for 0.333333h; Inert atmosphere;

With iodine; In tetrahydrofuran; at -45 - 25 ℃; Inert atmosphere;

(phenylethynyl)zinc chloride; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 50 ℃; for 2h; Inert atmosphere;
DOI:10.1039/b907330b

Reference yield:

: C₁₃H₁₀FIO₂S

: 536-74-3
phenylacetylene

: 1176869-75-2
[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Guidance literature:: phenylacetylene; With isopropylmagnesium bromide; In tetrahydrofuran; at 60 ℃; for 0.0833333h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; at 25 ℃; Inert atmosphere;

C₁₃H₁₀FIO₂S; With trifuran-2-yl-phosphane; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; at 50 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.201003657

Reference yield:

: 31401-23-7
p-methoxybenzenesulfinyl chloride

: 1176869-75-2
[5-[(4-methoxyphenyl)sulfinyl]-4-(phenylethynyl)-2-furyl](trimethyl)silane benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran / -20 - 25 °C / Inert atmosphere

2.1: 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride complex / tetrahydrofuran / -30 °C / Inert atmosphere

2.2: 25 °C / Inert atmosphere

3.1: isopropylmagnesium bromide / tetrahydrofuran / 0.08 h / 60 °C / Inert atmosphere

3.2: 25 °C / Inert atmosphere

3.3: 2 h / 50 °C / Inert atmosphere

With 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride complex; isopropylmagnesium bromide; In tetrahydrofuran;
DOI:10.1002/chem.201003657