4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

Base Information

Chemical Name:4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside
CAS No.:294639-17-1
Molecular Formula:C₃₅H₃₄N₄O₁₁
Molecular Weight:686.675
Hs Code.:

Synonyms:4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

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Chemical Property of 4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

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Technology Process of 4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

There total 2 articles about 4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 294639-15-9
2,3,6-tri-O-benzoyl-4-O-mesyl-N-(2,2-diethoxycarbonylvinyl)-β-D-galactopyranosylamine

: 294639-17-1
4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium azide; at 70 ℃; for 12h;
DOI:10.1016/S0957-4166(00)00212-3

Reference yield:

: 2-[((2R,3R,4S,5S,6R)-3,4-Bis-benzoyloxy-6-benzoyloxymethyl-2,5-dihydroxy-tetrahydro-pyran-2-ylamino)-methylene]-malonic acid diethyl ester

: 294639-17-1
4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / pyridine / 14 h / 20 °C

2: 92 percent / NaN₃; hexamethylphosphoramide / 12 h / 70 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium azide; 1: mesylation / 2: Substitution;
DOI:10.1016/S0957-4166(00)00212-3

Reference yield:

: 294639-17-1
4-azido-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

: 294639-19-3
4-amino-2,3,6-tri-O-benzoyl-4-deoxy-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranoside

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; at 20 ℃; for 10h; under 760 Torr;
DOI:10.1016/S0957-4166(00)00212-3