trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

Base Information

• Chemical Name: trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate
• CAS No.: 360048-28-8
• Molecular Formula: CF₃O₃S*C₆₅H₅₈NO₄P₂PtSi
• Molecular Weight: 1351.36

Synonyms:trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

Chemical Property of trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

Chemical Property:

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Technology Process of trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

There total 1 articles about trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

pyridine-4-carboxylic acid (55-22-1) + trans-iodo(tert-butyldiphenylsilylbenzoate-C(3))bis(triphenylphosphine)platinum(II) (360048-21-1) + silver trifluoromethanesulfonate (2923-28-6) → trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C3)bis(triphenylphosphine)platinum(II) triflate (360048-28-8)

Guidance literature:

In dichloromethane; byproducts: AgI; to a stirred soln. of complex in CH2Cl2 was added AgO3SCF3, the mixt. was stirred at room temp. for 16 h in the absence of light, AgI was filtered off, reduced in vol., isonicotinic acid was added, the mixt. was stirred for 17 h at room temp. (N2); the solvent was removed in vac., recrystd. from CH2Cl2/diethyl ether; elem. anal.;

DOI:10.1021/om010127c

Reference yield: 65.0%

trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C3)bis(triphenylphosphine)platinum(II) triflate (360048-28-8) → trans-(benzoic acid-C3)(isonicotinic acid)bis(triphenylphosphine)platinum(II) triflate (360048-36-8)

Guidance literature:

With CF₃SO₃H; In dichloromethane; to a stirred soln. of complex in CH2Cl2 was added CF3SO3H, the mixt. wasstirred at room temp. for 2 h (N2); diethyl ether was added, ppt. was filtered off, washed with diethyl ether, dried in vac., recrystd. from CH2Cl2/diethyl ether; elem. anal.;

DOI:10.1021/om010127c

upstream raw materials:

pyridine-4-carboxylic acid

trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II)

silver trifluoromethanesulfonate

Downstream raw materials:

trans-(benzoic acid-C₃)(isonicotinic acid)bis(triphenylphosphine)platinum(II) triflate

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