Technology Process of (η5-C5H5)Ni(P(C6H5)3)2
There total 10 articles about (η5-C5H5)Ni(P(C6H5)3)2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
(C5H5)Na;
In
tetrahydrofuran;
25°C, under N2;
DOI:10.1021/ja00410a044
- Guidance literature:
-
With
triphenylphosphine;
In
benzene-d6;
byproducts: (C5H5)2Ni, (C5H5)(C5H4CH3)Ni, Ni(P(C6H5)3)4; Irradiation (UV/VIS); further byproduct: CH4; degassing the soln., sealing in a NMR tube, photolysis at .lamda.>413 nm, cooling by immersion in an ice bath at -6°C during photolysis; monitoring by NMR and ESR;
DOI:10.1016/S0277-5387(00)86237-3
- Guidance literature:
-
With
triphenylphosphine;
In
benzene-d6;
byproducts: (C5H4C2H5)Ni(P(C6H5)3)2, (C5H5)2Ni, (C5H5)(C5H4C2H5)Ni; Irradiation (UV/VIS); further byproducts: Ni(P(C6H5)3)4, ethane, ethylene; degassing the soln., sealing in a NMR tube, photolysis at .lamda.>413 nm, cooling by immersion in an ice bath at -6°C during photolysis; monitoring by NMR and ESR;
DOI:10.1016/S0277-5387(00)86237-3
