chlorotris(triphenylphosphine)nickel

Base Information

• Chemical Name: chlorotris(triphenylphosphine)nickel
• CAS No.: 15169-64-9
• Molecular Formula: C₅₄H₄₅ClNiP₃
• Molecular Weight: 881.016
• Mol file: 15169-64-9.mol

Synonyms:chlorotris(triphenylphosphine)nickel

Chemical Property of chlorotris(triphenylphosphine)nickel

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chlorotris(triphenylphosphine)nickel

There total 19 articles about chlorotris(triphenylphosphine)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

bis(triphenylphosphine)dichlorocobalt(II) (14126-40-0,22327-14-6) + tetrakis(triphenylphosphine)nickel(0) (15133-82-1) → chlorotris(triphenylphosphine)cobalt(I) (26305-75-9) + chlorotris(triphenylphosphine)nickel (15169-64-9)

Guidance literature:

In acetone; 5 h shaking at room temp.; filtration of cryst. Co complex, evapn. of filtrate, pptn. of Ni complex;

Reference yield: 83.0%

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + tetrakis(triphenylphosphine)nickel(0) (15133-82-1) → chlorotris(triphenylphosphine)nickel (15169-64-9)

Guidance literature:

In diethyl ether; at 20 ℃; for 5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.5b08612

Reference yield: 77.0%

nickel(II) chloride hexahydrate + triphenylphosphine (603-35-0) → chlorotris(triphenylphosphine)nickel (15169-64-9)

Guidance literature:

With lithium borohydride; In ethanol; at 20 ℃; for 2.5h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.inorgchem.5b02497

upstream raw materials:

bis(triphenylphosphine)dichlorocobalt(II)

tetrakis(triphenylphosphine)nickel⁽⁰⁾

bis(triphenylphosphine)ethylenenickel⁽⁰⁾

acetyl chloride

Downstream raw materials:

Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF

nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide

chlorobis(triphenylphosphine)nickel(I) tetrahydrofuran solvate

bis(triphenylphosphine)nickel(II) chloride