tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

Base Information

Chemical Name:tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate
CAS No.:102861-57-4
Molecular Formula:C₂₂H₃₈O₄Si
Molecular Weight:394.627
Hs Code.:

Synonyms:tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

Chemical Property:

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Technology Process of tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

There total 4 articles about tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.2%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 99315-47-6
tert-butyl (3S,4S)-3-hydroxy-4-(benzyloxy)pentanoate

: 102861-57-4
tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 15h;
DOI:10.1016/j.tetlet.2008.02.033

Reference yield:

: 32368-18-6
α-thiomethoxyacetic acid tert-butyl ester

: 102861-57-4
tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

Guidance literature:: Multi-step reaction with 3 steps

1: LDA / tetrahydrofuran / -78 °C

2: MgBr₂ / CH₂Cl₂ / 36 h / 0 °C

3: 2.) Raney Ni

With nickel; magnesium bromide; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)98666-0

Reference yield:

: 102861-56-3
((Z)-1-tert-Butoxy-2-methylsulfanyl-vinyloxy)-trimethyl-silane

: 102861-57-4
tert-butyl (3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-(benzyloxy)pentanoate

Guidance literature:: Multi-step reaction with 2 steps

1: MgBr₂ / CH₂Cl₂ / 36 h / 0 °C

2: 2.) Raney Ni

With nickel; magnesium bromide; In dichloromethane;
DOI:10.1016/S0040-4039(00)98666-0