(S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid

Base Information

• Chemical Name: (S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid
• CAS No.: 1429753-14-9
• Molecular Formula: C₂₃H₂₂BFeO₂P
• Molecular Weight: 428.058
• Mol file: 1429753-14-9.mol

Synonyms:(S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid

Chemical Property of (S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid

Chemical Property:

Purity/Quality:

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Technology Process of (S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid

There total 1 articles about (S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

carbon dioxide (124-38-9,18923-20-1) + (S)-ferrocenyl-(o-bromophenyl)phenylphosphine borane (1383686-41-6,1383809-86-6) → (S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid (1429753-14-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol400515e

Reference yield: 61.0%

(S)-ferrocenyl-(2-carboxylic-phenyl)phenylphosphine borane acid (1429753-14-9) → (S)-ferrocenyl-[(2-hydroxymethyl)phenyl]phenylphosphine borane (1429753-13-8)

Guidance literature:

With dimethylsulfide borane complex; In tetrahydrofuran; at 0 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1021/ol400515e

upstream raw materials:

carbon dioxide

(S)-ferrocenyl-(o-bromophenyl)phenylphosphine borane

Downstream raw materials:

(S)-ferrocenyl-[(2-hydroxymethyl)phenyl]phenylphosphine borane