Technology Process of C34H48O13S
There total 40 articles about C34H48O13S which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
4-methyl-morpholine;
In
dichloromethane;
at 20 ℃;
DOI:10.1021/ja042686r
- Guidance literature:
-
Multi-step reaction with 9 steps
1: 88 percent / NaBH4; CeCl3*7H2O / CH2Cl2; methanol / 0.5 h / 0 °C
2: 83 percent / NaHCO3; mCPBA / CH2Cl2 / 11.5 h / 20 °C
3: 81 percent / N-methylmorpholine-N-oxide; tetra-n-propylammonium perruthenate; 4A molecular sieves / CH2Cl2 / 1 h / 20 °C
4: 100 percent / Na[PhSeB(OEt)3] / ethanol / 0 - 20 °C
5: camphorsulfonic acid / CH2Cl2 / 4 h / 20 °C
6: L-Selectride / tetrahydrofuran / 0.75 h / -78 °C
7: 78.8 mg / LiAlH4 / tetrahydrofuran / 0.67 h / 0 °C
8: 81 percent / Et3N; DMAP / CH2Cl2 / 20 °C
9: 98 percent / N-methylmorpholine / CH2Cl2 / 20 °C
With
4-methyl-morpholine; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; cerium(III) chloride; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; L-Selectride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; sodium phenylseleno(triethyl)borate; triethylamine; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; methanol; ethanol; dichloromethane;
1: Luche reduction;
DOI:10.1021/ja042686r
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 83 percent / NaHCO3; mCPBA / CH2Cl2 / 11.5 h / 20 °C
2: 81 percent / N-methylmorpholine-N-oxide; tetra-n-propylammonium perruthenate; 4A molecular sieves / CH2Cl2 / 1 h / 20 °C
3: 100 percent / Na[PhSeB(OEt)3] / ethanol / 0 - 20 °C
4: camphorsulfonic acid / CH2Cl2 / 4 h / 20 °C
5: L-Selectride / tetrahydrofuran / 0.75 h / -78 °C
6: 78.8 mg / LiAlH4 / tetrahydrofuran / 0.67 h / 0 °C
7: 81 percent / Et3N; DMAP / CH2Cl2 / 20 °C
8: 98 percent / N-methylmorpholine / CH2Cl2 / 20 °C
With
4-methyl-morpholine; dmap; lithium aluminium tetrahydride; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; L-Selectride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; sodium phenylseleno(triethyl)borate; triethylamine; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/ja042686r