Z-phenyl β-chlorovinyl selenide

Base Information

• Chemical Name: Z-phenyl β-chlorovinyl selenide
• CAS No.: 95391-76-7
• Molecular Formula: C₈H₇ClSe
• Molecular Weight: 217.557
• Mol file: 95391-76-7.mol

Synonyms:Z-phenyl β-chlorovinyl selenide

Chemical Property of Z-phenyl β-chlorovinyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Z-phenyl β-chlorovinyl selenide

There total 7 articles about Z-phenyl β-chlorovinyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroacetylene (593-63-5) + Benzeneselenol (645-96-5) → (E)-1-phenylselenyl-2-chloroethylene (26620-09-7) + Z-phenyl β-chlorovinyl selenide (95391-76-7)

Guidance literature:

In diethyl ether; at 0 ℃; for 11h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference yield:

chloroacetylene (593-63-5) + diphenyl diselenide (1666-13-3) → 1-phenylselenoethyl ethyl ether (56814-37-0) + Z-phenyl β-chlorovinyl selenide (95391-76-7)

Guidance literature:

at 20 ℃; for 6.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference yield:

1,2-Dichloroethylene (540-59-0,43695-79-0) + Benzeneselenol (645-96-5) → Z-phenyl β-chlorovinyl selenide (95391-76-7)

Guidance literature:

With sodium hydroxide; benzyltri(n-butyl)ammonium chloride; In water; for 18h; Yield given; Heating;

upstream raw materials:

cis-1,2-Dichloroethylene

sodium phenylselenide

diethyl ether

diphenyl diselenide

Downstream raw materials:

((Z)-2-Ethylselanyl-vinylselanyl)-benzene

((Z)-2-Methylselanyl-vinylselanyl)-benzene

(Z)-β-styryl,(Z)-phenylselenyl-1-ethenyl selenide

{[(Z)-2-phenylselenylethenyl]selenyl}benzene

Refernces

• 1、 Martynov, A. V.,Mirskova, A. N.,Voronkov, M. G.. "CHLOROVINYLATION OF BENZENESELENOL AND ORGANIC DISELENIDES BY CHLORO- AND DICHLOROACETYLENES". . p. 1326 - 1328. Retrieved 2007/10/02.
• 2、 Martynov, A. V.,Mirskova, A. N.,Voronkov, M. G.. "PHASE-TRANSFER CATALYSIS IN THE SYNTHESIS OF ARYL MONO- AND DICHLOROVINYL SELENIDES". . p. 2257 - 2258. Retrieved 2007/10/02.