bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine

Base Information

• Chemical Name: bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine
• CAS No.: 112991-26-1
• Molecular Formula: C₂₀H₂₀N₂O₅S₂
• Molecular Weight: 432.521
• Mol file: 112991-26-1.mol

Synonyms:bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine

Chemical Property of bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine

There total 4 articles about bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis-benzenesulfonyl-(2,4,6-trimethyl-[3]pyridyl)-amine (34456-74-1) → bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine (112991-26-1)

Guidance literature:

With dihydrogen peroxide; acetic acid; at 80 - 90 ℃;

DOI:10.1021/ja01547a045

Reference yield:

2,4,6-trimethyl-3-amino-pyridine (51467-70-0) → bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine (112991-26-1)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine

2: H₂O₂; acetic acid / 80 - 90 °C

With dihydrogen peroxide; acetic acid; triethylamine;

DOI:10.1021/ja01547a045

Reference yield:

2,4,6-trimethyl-3-nitro-pyridine (21203-55-4) → bis-benzenesulfonyl-(2,4,6-trimethyl-1-oxy-[3]pyridyl)-amine (112991-26-1)

Guidance literature:

Multi-step reaction with 3 steps

1: N₂H₄+H₂O; Raney nickel; methanol

2: triethylamine

3: H₂O₂; acetic acid / 80 - 90 °C

With methanol; dihydrogen peroxide; nickel; hydrazine hydrate; acetic acid; triethylamine;

DOI:10.1021/ja01547a045

upstream raw materials:

bis-benzenesulfonyl-(2,4,6-trimethyl-[3]pyridyl)-amine

2,4,6-trimethyl-3-amino-pyridine

2,4,6-trimethyl-3-nitro-pyridine

benzenesulfonyl chloride