allyl 3,5-dimethylbenzoate

Base Information

• Chemical Name: allyl 3,5-dimethylbenzoate
• CAS No.: 1372715-42-8
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.242
• Mol file: 1372715-42-8.mol

Synonyms:allyl 3,5-dimethylbenzoate

Chemical Property of allyl 3,5-dimethylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of allyl 3,5-dimethylbenzoate

There total 2 articles about allyl 3,5-dimethylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-dimethylbenzoic acid (499-06-9) + allyl alcohol (107-18-6) → allyl 3,5-dimethylbenzoate (1372715-42-8)

Guidance literature:

3,5-dimethylbenzoic acid; allyl alcohol; With dmap; In dichloromethane; at 0 ℃; for 0.25h;

With dicyclohexyl-carbodiimide; In dichloromethane;

DOI:10.1002/anie.201106619

Reference yield:

3,5-dimethylbenzoic acid (499-06-9) + allyl bromide (106-95-6) → allyl 3,5-dimethylbenzoate (1372715-42-8)

Guidance literature:

With sodium hydrogencarbonate; In N,N-dimethyl-formamide; at 50 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jacs.0c03708

Reference yield: 83.0%

allyl 3,5-dimethylbenzoate (1372715-42-8) + Methyl phenyldiazoacetate (22979-35-7) → 1-methoxy-1-oxo-2-phenylpent-4-en-2-yl 3,5-dimethylbenzoate (1372715-47-3)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trifuran-2-yl-phosphane; In acetonitrile; at 90 ℃; for 0.666667h; Inert atmosphere;

DOI:10.1002/anie.201106619

upstream raw materials:

3,5-dimethylbenzoic acid

allyl alcohol

allyl bromide

Downstream raw materials:

1-methoxy-1-oxo-2-phenylpent-4-en-2-yl 3,5-dimethylbenzoate