IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

Base Information

Chemical Name:IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)
CAS No.:102844-69-9
Molecular Formula:C₂₉H₃₃ClIrO₃P
Molecular Weight:688.226
Hs Code.:

Synonyms:IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

Suppliers and Price of IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

There total 1 articles about IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 4731-65-1
tris(o-methoxyphenyl)phosphine

: 102844-69-9
IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

Guidance literature:: In dichloromethane; under N2 or Ar: (IrCl(COD))2 and PAn3 dissolved in CH2Cl2, vigorously stirred for 30 min at room temp.; pptd. (ethanol), filtered off, washed (ethanol, n-pentane), crystd. (ethanol/CH2Cl2), elem. anal.;
DOI:10.1016/j.molcata.2008.11.013

Reference yield: 88.0%

: 110-86-1
pyridine

: ammonium hexafluorophosphate

: 102844-69-9
IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

: 128278-87-5
[Ir(tris(ortho-anisyl)phosphine)(pyridine)(1,5-cyclo-octadiene)]PF₆

Guidance literature:: In methanol; under N2 or Ar: suspn. of IrCl(PAn3)(COD) in MeOH treated with excess ofpyridine under stirring for 60 min, NH4PF6 added; concn. under vac., filtration, washing (water, methanol, diethyl ether),vac. drying;
DOI:10.1016/j.molcata.2008.11.013

Reference yield: 81.0%

: ammonium hexafluorophosphate

: 102844-69-9
IrCl(tris(ortho-anisyl)phospine)(1,5-cyclo-octadiene)

: 7650-89-7
tribenzylphosphine

: [Ir(tris(ortho-anisyl)phosphine)(tribenzylphosphine)(1,5-cyclo-octadiene)]PF₆

Guidance literature:: With AgOSO₂CF₃; ethanol; In acetone; under N2 or Ar: acetone soln. of IrCl(PAn3)(COD) treated with AgOSO2CF3 under vigorous stirring for 30 min, soln. filtered out, PBz3, NH4PF6 andethanol added; pptd. under N2, filtered, washed (ethanol, n-pentane), vac. dried;
DOI:10.1016/j.molcata.2008.11.013