<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

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Chemical Name:<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane
CAS No.:149157-47-1
Molecular Formula:C₃₂H₄₈O₄Si
Molecular Weight:524.816
Hs Code.:

Synonyms:<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

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Chemical Property of <2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

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Technology Process of <2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

There total 5 articles about <2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 149157-46-0
<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(2-hydroxy-1,3-dimethyl-6-phenyl-5-hexenyl)-1,3-dioxane

: 149157-47-1
<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

Guidance literature:: With lutidine; In dichloromethane; at 0 ℃;
DOI:10.1016/S0040-4039(00)77580-0

Reference yield:

: 141423-25-8
<<3-(2R,4S,5S,6R,8E),4R>-3-(5-Hydroxy-2,4,6-trimethyl-1,3-dioxo-9-phenyl-8-nonenyl)-4-(phenylmethyl)>-2-oxazolidinone

: 149157-47-1
<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 4 steps

1: 81 percent / NaBH(OAc)3, AcOH / 1 h / 23 °C

2: 94 percent / LiBH₄ / methanol; tetrahydrofuran / 1 h / 0 °C

3: 91 percent / camphorsulfonic acid / dimethylformamide / 12 h / 23 °C

4: 100 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

With 2,6-dimethylpyridine; lithium borohydride; camphor-10-sulfonic acid; sodium tris(acetoxy)borohydride; acetic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00077a049

Reference yield:

: 149157-45-9
<2S,3S,4S,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-non-8-ene-1,3,5-triol

: 149157-47-1
<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / camphorsulfonic acid / dimethylformamide / 12 h / 23 °C

2: 100 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 °C

With 2,6-dimethylpyridine; camphor-10-sulfonic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00077a049