(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

Base Information

Chemical Name:(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene
CAS No.:171013-21-1
Molecular Formula:C₃₁H₃₄O₆
Molecular Weight:502.607
Hs Code.:

Synonyms:(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

Chemical Property:

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Technology Process of (2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

There total 7 articles about (2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: (2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-<oxy>-1-propyl>-2,6,8-trimethoxynaphthalene

: 171013-21-1
(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

Guidance literature:: With tri-n-butyl-tin hydride; In toluene; for 0.5h;
DOI:10.1021/ja00149a012

Reference yield:

: 100-39-0
benzyl bromide

: 171013-21-1
(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

Guidance literature:: Multi-step reaction with 6 steps

1: 47 percent / NaH, n-Bu₄NI / dimethylformamide / 12 h / 25 °C

2: 70 percent / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

3: 71 percent / MnO₂ / diethyl ether / 1 h / 23 °C

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, -78 deg C, 30 min

5: 78 percent / tetrahydrofuran / 18 h / Heating

6: 54 percent / (n-Bu)3SnH / toluene / 0.5 h

With manganese(IV) oxide; lithium aluminium tetrahydride; n-butyllithium; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja00149a012

Reference yield:

: 132019-89-7
methyl 2,6,8-trimethoxy-1-hydroxynaphthalene-3-carboxylate

: 171013-21-1
(2'S)-1-benzoxy-3-<2-(benzoxymethoxy)-1-propyl>-2,6,8-trimethoxynaphthalene

Guidance literature:: Multi-step reaction with 6 steps

1: 47 percent / NaH, n-Bu₄NI / dimethylformamide / 12 h / 25 °C

2: 70 percent / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

3: 71 percent / MnO₂ / diethyl ether / 1 h / 23 °C

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, -78 deg C, 30 min

5: 78 percent / tetrahydrofuran / 18 h / Heating

6: 54 percent / (n-Bu)3SnH / toluene / 0.5 h

With manganese(IV) oxide; lithium aluminium tetrahydride; n-butyllithium; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja00149a012