2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

Base Information

Chemical Name:2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran
CAS No.:577778-98-4
Molecular Formula:C₆₀H₅₆O₈S
Molecular Weight:937.166
Hs Code.:

Synonyms:2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

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Chemical Property of 2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

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Technology Process of 2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

There total 7 articles about 2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 527758-63-0
S-(2-tetrahydropyranyl)-4-hydroxythiophenol

: 577778-93-9
C₄₉H₄₃BrO₆

: 577778-98-4
2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

Guidance literature:: With 18-crown-6 ether; potassium carbonate; In acetone; for 72h; Heating;
DOI:10.1021/ja035515f

Reference yield:

: 2150-45-0
methyl 2,6-dihydroxybenzoate

: 577778-98-4
2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / K₂CO₃; 18-crown-6 / acetone / 72 h / Heating

2: 98 percent / LiAlH₄ / tetrahydrofuran / 2 h / 0 °C

3: 87 percent / PBr₃; 2,6-di-tert-butyl-4-methylpyridine / diethyl ether / 1 h / 0 °C

4: 49 percent / K₂CO₃; 18-crown-6 / acetone / 72 h / Heating

With lithium aluminium tetrahydride; 2,6-di-tert-butyl-4-methylpyridine; 18-crown-6 ether; phosphorus tribromide; potassium carbonate; In tetrahydrofuran; diethyl ether; acetone;
DOI:10.1021/ja035515f

Reference yield:

: 637-89-8
4-sulfanylphenol

: 577778-98-4
2-{4-[2,6-bis-(2,6-bis-benzyloxy-benzyloxy)-benzyloxy]-phenylsulfanyl}-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: pyridinum-p-toluenesulfonate / CH₂Cl₂ / 20 °C

2: 10.5 g / aq. HCl / methanol / 4 h

3: 49 percent / K₂CO₃; 18-crown-6 / acetone / 72 h / Heating

With hydrogenchloride; 18-crown-6 ether; pyridinium p-toluenesulfonate; potassium carbonate; In methanol; dichloromethane; acetone;
DOI:10.1021/ja035515f