Technology Process of 1,9-diformyl-5-phenyl-BODIPY
There total 1 articles about 1,9-diformyl-5-phenyl-BODIPY which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
1,9-diformyl-5-phenyldipyrrylmethane;
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
toluene;
at 90 ℃;
for 1h;
boron trifluoride diethyl etherate;
With
triethylamine;
In
toluene;
for 0.5h;
DOI:10.1039/c4cc02567a
- Guidance literature:
-
(4,5-Bis-methylsulfanyl-[1,3]dithiol-2-yl)-phosphonic acid diethyl ester;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.5h;
Inert atmosphere;
1,9-diformyl-5-phenyl-BODIPY;
In
tetrahydrofuran; hexane;
at -78 - 20 ℃;
for 0.5h;
Inert atmosphere;
DOI:10.1039/c4cc02567a
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
1.2: 0.5 h / -78 - 20 °C / Inert atmosphere
2.1: dichloromethane / 24.84 °C
With
n-butyllithium;
In
tetrahydrofuran; hexane; dichloromethane;
1.1: |Horner-Wadsworth-Emmons Olefination / 1.2: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1039/c4cc02567a
