Ph₃PAu[N(TeP(i-Pr)2)2]

Base Information

• Chemical Name: Ph₃PAu[N(TeP(i-Pr)2)2]
• CAS No.: 936910-85-9
• Molecular Formula: C₃₀H₄₃AuNP₃Te₂
• Molecular Weight: 962.766
• Mol file: 936910-85-9.mol

Synonyms:Ph₃PAu[N(TeP(i-Pr)2)2]

Chemical Property of Ph₃PAu[N(TeP(i-Pr)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ph₃PAu[N(TeP(i-Pr)2)2]

There total 2 articles about Ph₃PAu[N(TeP(i-Pr)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

[(tetramethylethylenediamine)Na(TeP(i-Pr)2)2N] + triphenylphosphine (603-35-0) + gold(I) chloride (10294-29-8,11118-27-7) → Ph3PAu[N(TeP(i-Pr)2)2] (936910-85-9)

Guidance literature:

In tetrahydrofuran; addn. of soln. of PPh3 in THF to a stirred suspn. of AuCl in THF at 23 °C, addn. to a stirred soln. of Na salt at -78 °C over 30 min, warming to 23 °C over 1 h; removal of solvent in vac., addn. of ether, filtration, concn., standingat -18 °C for 24 h, sepn. of ppt. by decantation, washing with c old hexane, elem. anal.;

DOI:10.1039/b617429a

Reference yield:

(Au(μ-Te)[TeP(i)Pr2NP(i)Pr2])2 (1122593-24-1) + triphenylphosphine (603-35-0) → Ph3PAu[N(TeP(i-Pr)2)2] (936910-85-9)

Guidance literature:

In not given; identified by NMR;

DOI:10.1139/V08-074

Reference yield:

Ph3PAu[N(TeP(i-Pr)2)2] (936910-85-9) → calaverite + gold (7440-57-5,457905-15-6)

Guidance literature:

In toluene; deposition of aerosol of toluene soln. of complex on glass at 350-500 °C for 60 min under Ar;

DOI:10.1039/b617429a

upstream raw materials:

triphenylphosphine

gold(I) chloride

(Au(μ-Te)[TeP(i)Pr2NP(i)Pr2])2

Downstream raw materials:

gold