Synonyms:gold(1+) chloride;GOLD MONOCHLORIDE [MI];CHEBI:30078;AKOS016009901
99%, *data from raw suppliers
There total 24 articles about Gold(1+) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
Reference yield: 83.0%
Reference yield: 60.0%
Reference yield:
The research presents an efficient method for synthesizing 1-aminoisoquinolines, which are important components in pharmacophores and natural products, through a silver triflate and gold(I) chloride cocatalyzed reaction of 2-alkynylbenzaldoximes with isocyanoacetates. The study explores the role of gold(I) cation in activating the isocyanide substrate and provides a unique pathway for substrate activation. The experiments involved the use of various reactants, including 2-alkynylbenzaldoximes and 2-isocyanoacetates, with silver triflate and gold(I) chloride as catalysts, and triethylamine as a base, in tetrahydrofuran as the solvent at 70 °C. The analysis of the synthesized products included techniques such as infrared spectroscopy (IR), nuclear magnetic resonance (NMR), mass spectrometry (MS), and high-resolution mass spectrometry (HRMS) to confirm the structure and purity of the 1-aminoisoquinolines obtained in good to excellent yields.
The research focuses on the cis-selective single-cleavage skeletal rearrangement of 1,6-enynes in metal-catalyzed cycloisomerizations, aiming to reveal the multifaceted character of the intermediates involved in these reactions. The study explores the factors controlling the selectivity in the rearrangement of 1,6-enynes, which can lead to different types of products depending on the catalyst used. The researchers concluded that the cis-selective single-cleavage rearrangement of enynes has revealed an unrecognized aspect of gold intermediates in cycloisomerization and related reactions of enynes, where reactions are generally stereospecific but become non-stereospecific in the presence of strongly electron-donating substituents. The chemicals used in the process include various 1,6-enynes, gold catalysts such as AuCl, AuCl(oTol3P), and cationic AuI catalysts, as well as other metal catalysts like PtCl4, GaCl3, and InCl3.
The research focuses on the preparation and structural characterization of gold(I) phosphinine complexes, specifically [AuCl(C5H2P-2,6-Me2-4-Ph)] and [AuCl(C5H2P-2,4,6-Ph3)], using single-crystal X-ray diffraction studies. The conclusions drawn from the research indicate that in the case of [AuCl(C5H2P-2,6-Me2-4-Ph)], the molecules form crossed dimers in the crystal with a weak aurophilic interaction, while [AuCl(C5H2P-2,4,6-Ph3)] exhibits intermolecular Au···π interactions with the phosphinine ring, marking it as the first structurally characterized example of such interactions involving a heteroarene. The chemicals used in the process include gold(I) chloride, phosphinine ligands (C5H2P-2,6-Me2-4-Ph and C5H2P-2,4,6-Ph3), tetrahydrothiophene (THT), and dichloromethane as a solvent.
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