[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

Base Information

Chemical Name:[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid
CAS No.:1313760-26-7
Molecular Formula:C₈H₇NO₄
Molecular Weight:182.141
Hs Code.:

[<sup>(15)</sup>N]2-amino-1,4-benzenedicarboxylic acid

Synonyms:[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

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Chemical Property of [⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

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Technology Process of [⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

There total 2 articles about [⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1313760-27-8
diethyl 2-aminoterephthalate-15N

: 1313760-26-7
[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

Guidance literature:: With water; sodium hydroxide; In methanol; at 20 ℃; for 24h;
DOI:10.1016/j.molstruc.2011.07.037

Reference yield:

: 636-09-9
diethyl terephthalate

: 1313760-26-7
[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: [¹⁵N]-potassium nitrate; trifluorormethanesulfonic acid; phosphorus pentoxide / nitromethane / 8 h / 50 °C

2: palladium 10% on activated carbon; hydrogen / tetrahydrofuran / 24 h / 20 °C / 3750.38 Torr

3: water; sodium hydroxide / methanol / 24 h / 20 °C

With [¹⁵N]-potassium nitrate; trifluorormethanesulfonic acid; phosphorus pentoxide; palladium 10% on activated carbon; water; hydrogen; sodium hydroxide; In tetrahydrofuran; methanol; nitromethane;
DOI:10.1016/j.molstruc.2011.07.037

Reference yield:

: 1313760-26-7
[⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylic acid

: 10026-11-6
zirconium(IV) chloride

: ([Zr₆O₄(OH)4([⁽¹⁵⁾N]2-amino-1,4-benzenedicarboxylate)4([⁽¹⁵⁾N]2-ammonium-1,4-benzenedicarboxylate)2]Cl₂)n

Guidance literature:: In N,N-dimethyl-formamide; prepn. of DMF solns. of ZrCl4 and aminobenzenedicarboxylic acid by dissolving at 85°C under sonication, mixing solns., heating at 120°C for 24 h; washing with DMF for 30 min, keeping in methanol for 24 h, decantation, repeating over 5 ds, heating at 120°C and 30 mTorr for 48 h, (15)N NMR;
DOI:10.1021/ic200744y