(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

Base Information

Chemical Name:(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]
CAS No.:1207750-82-0
Molecular Formula:C₅₂H₅₆ClN₅O₁₄S
Molecular Weight:1042.56
Hs Code.:

(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

Synonyms:(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

Suppliers and Price of (2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

There total 1 articles about (2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1207750-80-8
phenyl 2-azido-3,4-di-O-benzyl-6-O-chloroacetyl-2-deoxy-1-thio-α,β-D-glucopyranoside

: 1207750-78-4
tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate

: 1207750-82-0
(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

Guidance literature:: phenyl 2-azido-3,4-di-O-benzyl-6-O-chloroacetyl-2-deoxy-1-thio-α,β-D-glucopyranoside; tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate; In diethyl ether; dichloromethane; at -30 ℃; for 1h; Molecular sieve; Inert atmosphere;

With Me₂S₂-Tf₂O; In diethyl ether; dichloromethane; for 0.0833333h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1016/j.tetlet.2009.11.042

Reference yield: 74.0%

: 1207750-82-0
(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

: 1207750-84-2
(2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-[tert-butyl (2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol)uronate]

Guidance literature:: With hydrazinedithiocarboxylate; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;
DOI:10.1016/j.tetlet.2009.11.042

Reference yield: 66.0%

: 1207750-82-0
(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]

: 108-24-7
acetic anhydride

: 1252027-51-2
(2-acetamido-3,4-di-O-benzyl-6-O-chloroacetyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-[tert-butyl (2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol)uronate]

Guidance literature:: (2-azido-3,4-di-O-benzyl-2-deoxy-6-O-chloroacetyl-α-D-glucopyranosyl)-(1->4)-[tert-butyl [2,3-di-O-benzyl-1,5-dideoxy-1,5-imino-N-(4-nitro)benzenesulfonyl-L-iditol]uronate]; With trimethylphosphane; In tetrahydrofuran; toluene; at 20 ℃; Inert atmosphere;

acetic anhydride; In tetrahydrofuran; toluene; at 20 ℃; for 24h;
DOI:10.1016/j.tet.2010.07.055