methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

Base Information

Chemical Name:methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate
CAS No.:134039-37-5
Molecular Formula:C₂₁H₂₁N₃O₁₂S₂
Molecular Weight:571.543
Hs Code.:

methyl 1,2-dihydroxy-5-<N,N-di(p-nitrobenzenesulphonyl)aminomethyl>cyclohex-3-ene-1-carboxylate

Synonyms:methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

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Chemical Property of methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

Chemical Property:

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Technology Process of methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

There total 5 articles about methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 134039-35-3
methyl 5-cyclohexa-1,3-diene-1-carboxylate

: 134039-37-5
methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3α,4α-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

Guidance literature:: With osmium(VIII) oxide;
DOI:10.1016/S0040-4039(00)92128-2

Reference yield:

: 134039-34-2
methyl 5-cyclohexa-1,3-diene-1-carboxylate

: 134039-37-5
methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) DMF, 20 deg C, 1 h, 2.) 1.5 h

2: 10 percent / N-methylmorpholine N-oxide / OsO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 24 h / 20 °C

With sodium hydride; 4-methylmorpholine N-oxide; osmium(VIII) oxide; In water; acetone; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)89449-7

Reference yield:

: 134039-44-4
methyl 5-(aminomethyl)cyclohexa-1,3-diene-1-carboxylate

: 134039-37-5
methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / Et₃N / tetrahydrofuran / 40 h / 20 °C

2: 1.) NaH / 1.) DMF, 20 deg C, 1 h, 2.) 1.5 h

3: 10 percent / N-methylmorpholine N-oxide / OsO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 24 h / 20 °C

With sodium hydride; 4-methylmorpholine N-oxide; triethylamine; osmium(VIII) oxide; In tetrahydrofuran; water; acetone; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)89449-7