Methyl cyclobutanemethanol, α-methyl-

Base Information

• Chemical Name: Methyl cyclobutanemethanol, α-methyl-
• CAS No.: 38401-41-1
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• Mol file: 38401-41-1.mol

Synonyms:

Chemical Property of Methyl cyclobutanemethanol, α-methyl-

Chemical Property:

• Boiling Point: 144.5 °C at 760 mmHg
• Flash Point: 57.9 °C
• Density: 0.962 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl cyclobutanemethanol, α-methyl-

There total 1 articles about Methyl cyclobutanemethanol, α-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(3-Iodo-propyl)-2-methyl-oxirane (87453-03-0) → 1-methylcyclopentanol (1462-03-9) + (1-methylcyclobutyl)methanol (38401-41-1)

Guidance literature:

With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; Product distribution; Effect of additive or warming.;

DOI:10.1016/S0040-4039(00)89212-6

Reference yield: 54.0%

(1-methylcyclobutyl)methanol (38401-41-1) → 1-(bromo-methyl)-1-methyl-cyclobutane (98775-14-5)

Guidance literature:

With bromine; triphenylphosphine; In N,N-dimethyl-formamide; for 0.5h; Heating;

DOI:10.1016/0022-328X(88)83115-2

Reference yield:

(1-methylcyclobutyl)methanol (38401-41-1) + p-toluenesulfonyl chloride (98-59-9) → (1-methylcyclobutyl)methyl 4-methylbenzene-1-sulfonate

Guidance literature:

In pyridine; at 0 ℃;

upstream raw materials:

2-(3-Iodo-propyl)-2-methyl-oxirane

Downstream raw materials:

1-(bromo-methyl)-1-methyl-cyclobutane

(1-methylcyclobutyl)methyl brosylate

methyl 4'-[10-(1-methylcyclobutan-1-ylmethoxy)decyloxy]biphenyl-4-carboxylate

methyl 4'-[11-(1-methylcyclobutan-1-ylmethoxy)undecyloxy]biphenyl-4-carboxylate

Refernces