(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

Base Information

Chemical Name:(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate
CAS No.:130861-77-7
Molecular Formula:C₃₃H₂₈Br₂O₄
Molecular Weight:648.391
Hs Code.:

(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenz<a,j>anthracene-14-carboxylate

Synonyms:(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

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Chemical Property of (2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

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Technology Process of (2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

There total 5 articles about (2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 3970-21-6
2-Methoxyethoxymethyl chloride

: 130861-76-6
2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylic acid

: 130861-77-7
(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/ja00001a027

Reference yield:

: 32281-97-3
7-bromo-3,4-dihydro-2H-naphthalen-1-one

: 130861-77-7
(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: BF₃*Et₂O / 5 h / 100 °C

2: sodium hydride / tetrahydrofuran / 5 h / Ambient temperature

3: 1.) lithium triethylborohydride, 2.) 1 N aq. sodium hydroxide, 30percent aq. hydrogen peroxide / 1.) THF, RT, overnight, 2.) 0.5 h

4: 83 percent / N,N-diisopropylethylamine / CH₂Cl₂ / 1 h / 0 °C

With sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; lithium triethylborohydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00001a027

Reference yield:

: 116047-27-9
7-bromo-2-benzylidene-1-tetralone

: 130861-77-7
(2-methoxyethoxy)methyl 2,12-dibromo-7-phenyl-5,6,8,9-tetrahydrodibenzanthracene-14-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: BF₃*Et₂O / 5 h / 100 °C

2: sodium hydride / tetrahydrofuran / 5 h / Ambient temperature

3: 1.) lithium triethylborohydride, 2.) 1 N aq. sodium hydroxide, 30percent aq. hydrogen peroxide / 1.) THF, RT, overnight, 2.) 0.5 h

4: 83 percent / N,N-diisopropylethylamine / CH₂Cl₂ / 1 h / 0 °C

With sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; lithium triethylborohydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00001a027