Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

Base Information

Chemical Name:Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)
CAS No.:85956-36-1
Molecular Formula:C₂₆H₂₇NOPRe
Molecular Weight:586.687
Hs Code.:

Re(C<sub>5</sub>H<sub>5</sub>)(P(C<sub>6</sub>H<sub>5</sub>)3)(NO)(CH(CH<sub>3</sub>)2)

Synonyms:Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

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Chemical Property of Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

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Technology Process of Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

There total 2 articles about Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: synclinal-{(η5-C5H5)Re(NO)(PPh3)(CHCH3)}PF6

: 917-54-4
methyllithium

: 85956-36-1
Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

: (η(5)-C5H5)Re(NO)(PPh3)(CH=CH2)

Guidance literature:: In tetrahydrofuran; dichloromethane; a soln. of Re-complex in CH2Cl2 was cooled to -78°C, MeLi in THFwas added, stirred for 20 min at -78°C, warmed; evapd., extd. with C6H6, filtered through silica gel, evapd., dissolvedin hexanes, stored in a freezer overnight;
DOI:10.1021/ja00353a020

Reference yield:

: synclinal-{(η5-C5H5)Re(NO)(PPh3)(CHCH3)}PF6

: 75-16-1
methylmagnesium bromide

: 85956-36-1
Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

: (η(5)-C5H5)Re(NO)(PPh3)(CH=CH2)

Guidance literature:: In tetrahydrofuran; dichloromethane; a soln. of Re-complex in CH2Cl2 was cooled to -78°C, CH3MgBr in THF was added, stirred for 20 min at -78°C, warmed; evapd., extd. with C6H6, filtered through silica gel, evapd., dissolvedin hexanes, stored in a freezer overnight;
DOI:10.1021/ja00353a020

Reference yield: 72.0%

: 85956-36-1
Re(C₅H₅)(P(C₆H₅)3)(NO)(CH(CH₃)2)

: 437-17-2
tritylium hexafluorophosphate

: 85955-92-6
{(η5-C5H5)Re(NO)(PPh3)(H2C=CHCH3)}+PF6-

Guidance literature:: In dichloromethane; to a -78°C soln. of Re-complex in CH2Cl2 was added Ph3CPF6, stirred at low temp. for 10 min, hexanes added, warmed to room temp.; evapd., washed with hexanes, was taken up in CHCl3, crystd. by additionof ether, filtered;
DOI:10.1021/ja00353a020