Welcome to LookChem.com Sign In|Join Free
  • or

75-16-1

Post Buying Request

75-16-1 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
Methylmagnesium bromide Manufacturer/High quality/Best price/In stock
Cas No: 75-16-1
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Methylmagnesium Bromide supplier in China
Cas No: 75-16-1
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
methylmagnesium bromide sol.
Cas No: 75-16-1
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
Factory Supply Methylmagnesium bromide
Cas No: 75-16-1
No Data 1 1 Ality Chemical Corporation Contact Supplier
Methylmagnesium bromide
Cas No: 75-16-1
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Amadis Chemical offer CAS#75-16-1;CAT#A865727
Cas No: 75-16-1
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
75-16-1
Cas No: 75-16-1
No Data 1 Kilogram 1 Metric Ton/Week Henan Tianfu Chemical Co., Ltd. Contact Supplier
CAS NO.:75-16-1
Cas No: 75-16-1
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier
METHYLMAGNESIUM BROMIDE 75-16-1
Cas No: 75-16-1
No Data 1 Gram 2000 Metric Ton/Year Hunan chemfish Pharmaceutical co.,Ltd Contact Supplier
METHYLMAGNESIUM BROMIDE Organic magnesium
Cas No: 75-16-1
USD $ 10.0-15.0 / Kilogram 1 Kilogram 10000 Metric Ton/Month Baoji Guokang Healthchem co.,ltd Contact Supplier

75-16-1 Usage

Hazard

Flammable, dangerous fire and explosionrisk.

Fire Hazard

Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

Chemical Properties

Clear brown solution when properly stored

Health Hazard

Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Air & Water Reactions

Highly flammable. Reacts with water or moisture in the air to form flammable methane gas. The heat from this reaction may be sufficient to ignite the produced methane [AAR 1991]. Unstable peroxides may form with exposure of the ether to air. This is a slow process.

Definition

Available in solution inether.

Reactivity Profile

Organometallics, such as METHYL MAGNESIUM BROMIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.

Safety Profile

May ignite spontaneously in air. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

General Description

A colorless cloudy solution in diethyl ether. Flash point -49°F. Vapors heavier than air.
InChI:InChI=1/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1/rCH3Mg.BrH/c1-2;/h1H3;1H/q+1;/p-1

75-16-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (M0362)  Methylmagnesium Bromide (12% in Tetrahydrofuran, ca. 1mol/L)   75-16-1 250g 620.00CNY Detail
TCI America (M2237)  Methylmagnesium Bromide (ca. 30% in 2-Methyltetrahydrofuran, ca. 3mol/L)   75-16-1 250g 1,850.00CNY Detail
Alfa Aesar (87324)  Methylmagnesium bromide, 3M in ether    75-16-1 1mole 1140.0CNY Detail
Alfa Aesar (41252)  Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles    75-16-1 0.25mole 364.0CNY Detail
Alfa Aesar (41252)  Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles    75-16-1 1mole 1099.0CNY Detail
Aldrich (302430)  Methylmagnesiumbromidesolution  1.0 M in dibutyl ether 75-16-1 302430-100ML 1,503.45CNY Detail
Aldrich (302430)  Methylmagnesiumbromidesolution  1.0 M in dibutyl ether 75-16-1 302430-800ML 5,819.58CNY Detail
Aldrich (282235)  Methylmagnesiumbromidesolution  1.4 M in THF: toluene (1:3) 75-16-1 282235-100ML 596.70CNY Detail
Aldrich (282235)  Methylmagnesiumbromidesolution  1.4 M in THF: toluene (1:3) 75-16-1 282235-800ML 1,177.02CNY Detail
Aldrich (703583)  Methylmagnesiumbromidesolution  ~3.4 M in 2-methyltetrahydrofuran 75-16-1 703583-100ML 1,164.15CNY Detail
Aldrich (703583)  Methylmagnesiumbromidesolution  ~3.4 M in 2-methyltetrahydrofuran 75-16-1 703583-800ML 5,218.20CNY Detail

75-16-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Methylmagnesium bromide

1.2 Other means of identification

Product number -
Other names Methyl magnesium bromide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-16-1 SDS

75-16-1Synthetic route

1,2-dibromomethane
74-95-3

1,2-dibromomethane

A

propene
187737-37-7

propene

B

ethene
74-85-1

ethene

C

methylmagnesium bromide
75-16-1

methylmagnesium bromide

D

methylenedimagnesium dibromide
27329-47-1

methylenedimagnesium dibromide

E

MgBr2

MgBr2

Conditions
ConditionsYield
With amalgamated magnesium In diethyl ether; benzene at 0℃; special sealed glass apparatus; Further byproducts given;A n/a
B n/a
C n/a
D 50%
E n/a
methyl bromide
74-83-9

methyl bromide

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Conditions
ConditionsYield
With magnesium In diethyl ether Thermodynamic data; -ΔH(reaction);
With magnesium at -258.2℃; Product distribution; codeposition with other metals under matrix isolation conditions;
With magnesium In diethyl ether
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

E-β-(dibenzylchlorosilyl)styrene

E-β-(dibenzylchlorosilyl)styrene

A

methylmagnesium bromide
75-16-1

methylmagnesium bromide

B

C15H14ClF3O3SSi

C15H14ClF3O3SSi

Conditions
ConditionsYield
In dichloromethane
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

E-β-(benzyldiphenylsilyl)styrene

E-β-(benzyldiphenylsilyl)styrene

A

methylmagnesium bromide
75-16-1

methylmagnesium bromide

B

C20H17F3O3SSi

C20H17F3O3SSi

Conditions
ConditionsYield
In dichloromethane
methyl bromide
74-83-9

methyl bromide

magnesium

magnesium

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Conditions
ConditionsYield
With diethyl ether
2-benzofuran-1(3H)-one
87-41-2

2-benzofuran-1(3H)-one

methylmagnesium bromide
75-16-1

methylmagnesium bromide

α,α-dimethyl-o-xylene α,α'-diol
55549-01-4

α,α-dimethyl-o-xylene α,α'-diol

Conditions
ConditionsYield
at -78 - 20℃;100%
In tetrahydrofuran; diethyl ether at 30℃; for 12.5h;88%
unter Wasserabgabe entsteht 1.1-Dimethyl-phthalan;
methylmagnesium bromide
75-16-1

methylmagnesium bromide

α-methyl-trans-cinnamaldehyde
15174-47-7

α-methyl-trans-cinnamaldehyde

(E)-3-methyl-4-phenyl-but-3-en-2-ol
87422-10-4

(E)-3-methyl-4-phenyl-but-3-en-2-ol

Conditions
ConditionsYield
Stage #1: methylmagnesium bromide; α-methyl-trans-cinnamaldehyde In tetrahydrofuran; diethyl ether at 0℃; for 0.5h; Inert atmosphere;
Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether
100%
With diethyl ether
4-iodobenzoic acid ethyl ester
51934-41-9

4-iodobenzoic acid ethyl ester

methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-(4-iodophenyl)propan-2-ol
60514-82-1

2-(4-iodophenyl)propan-2-ol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 72h;100%
3-methoxy-5H-dibenzo[a,d]cyclohepten-5-one
22725-38-8

3-methoxy-5H-dibenzo[a,d]cyclohepten-5-one

methylmagnesium bromide
75-16-1

methylmagnesium bromide

3-methoxy-5-methyl-5H-dibenzocyclohepten-5-ol
125025-18-5

3-methoxy-5-methyl-5H-dibenzocyclohepten-5-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether for 6h; Ambient temperature;100%
10-Undecenal
112-45-8

10-Undecenal

methylmagnesium bromide
75-16-1

methylmagnesium bromide

dodec-11-en-2-ol
21951-49-5

dodec-11-en-2-ol

Conditions
ConditionsYield
In diethyl ether at -40℃; Grignard reaction;100%
In tetrahydrofuran at 0℃; Grignard reaction;90%
In tetrahydrofuran; diethyl ether at -40 - 25℃; for 15h; Inert atmosphere;83%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-5-(N-benzyl-p-toluenesulfonamido)-3-methyl-6-phenylhex-3-on-2-one
82495-72-5

(E)-5-(N-benzyl-p-toluenesulfonamido)-3-methyl-6-phenylhex-3-on-2-one

(E)-5-(N-benzyl-p-toluenefulfonamido)-2,3-dimethyl-6-phenylhex-3-en-2-ol
82536-02-5

(E)-5-(N-benzyl-p-toluenefulfonamido)-2,3-dimethyl-6-phenylhex-3-en-2-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether for 1h; -78 deg C -> 0 deg C;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

3-fluoro-5H-dibenzocyclohepten-5-one
93559-82-1

3-fluoro-5H-dibenzocyclohepten-5-one

3-fluoro-5-methyl-5H-dibenzocyclohepten-5-ol
125025-39-0

3-fluoro-5-methyl-5H-dibenzocyclohepten-5-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether for 6h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

6-(benzyloxy)-2,4-dimethylfuro<2,3-b>pyridine-5-carboxaldehyde
124098-64-2

6-(benzyloxy)-2,4-dimethylfuro<2,3-b>pyridine-5-carboxaldehyde

5-(1-hydroxyethyl)-6-(benzyloxy)-2,4-dimethylfuro<2,3-b>pyridine
124098-67-5

5-(1-hydroxyethyl)-6-(benzyloxy)-2,4-dimethylfuro<2,3-b>pyridine

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at 0℃; for 0.25h;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

N-methoxy-N-methylcinnamamide
80783-99-9, 124931-15-3, 113474-86-5

N-methoxy-N-methylcinnamamide

(E)-benzalacetone
1896-62-4

(E)-benzalacetone

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
In tetrahydrofuran; diethyl ether at 0 - 20℃; for 2h;98%
Stage #1: N-methoxy-N-methylcinnamamide With methyl 4-bromocinnamate; triethylsilyl trifluoromethyl sulfonate; triethylphosphine In toluene at 110℃; for 5h; Inert atmosphere;
Stage #2: methylmagnesium bromide In tetrahydrofuran; toluene at -78℃; Inert atmosphere;
Stage #3: With tetrabutyl ammonium fluoride In tetrahydrofuran; toluene for 0.5h; Inert atmosphere;
83%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

Benzoic acid (2S,3S)-2-formyl-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

Benzoic acid (2S,3S)-2-formyl-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

Benzoic acid (2R,3S)-2-(1-hydroxy-ethyl)-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

Benzoic acid (2R,3S)-2-(1-hydroxy-ethyl)-1-(4-methoxy-phenyl)-4-oxo-azetidin-3-yl ester

Conditions
ConditionsYield
In tetrahydrofuran at -45℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-3-(furan-2-yl)-N-methoxy-N-methylprop-2-enamide
134197-98-1

(E)-3-(furan-2-yl)-N-methoxy-N-methylprop-2-enamide

(E)-4-(furan-2-yl)but-3-en-2-one
623-15-4

(E)-4-(furan-2-yl)but-3-en-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-N-methoxy-N-methyl-3-(thiophen-2-yl)acrylamide
134197-97-0

(E)-N-methoxy-N-methyl-3-(thiophen-2-yl)acrylamide

(E)-4-(2-thienyl)but-3-en-2-one
874-83-9, 33603-63-3

(E)-4-(2-thienyl)but-3-en-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(1S,3R)-2,2-Dimethyl-3-phenyl-cyclopropanecarboxylic acid methoxy-methyl-amide
134197-91-4

(1S,3R)-2,2-Dimethyl-3-phenyl-cyclopropanecarboxylic acid methoxy-methyl-amide

[(1RS,3SR)-2,2-dimethyl-3-phenylcyclopropyl]ethanone
134197-90-3

[(1RS,3SR)-2,2-dimethyl-3-phenylcyclopropyl]ethanone

Conditions
ConditionsYield
100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-N-Methoxy-3-(6-methoxy-naphthalen-2-yl)-N-methyl-acrylamide
134197-96-9

(E)-N-Methoxy-3-(6-methoxy-naphthalen-2-yl)-N-methyl-acrylamide

4-(6'-methoxy-2'-naphthyl)-3-buten-2-one
127053-22-9

4-(6'-methoxy-2'-naphthyl)-3-buten-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-N-Methoxy-N-methyl-3-(3-phenoxy-phenyl)-acrylamide
134197-94-7

(E)-N-Methoxy-N-methyl-3-(3-phenoxy-phenyl)-acrylamide

(E)-1-(3-Phenoxyphenyl)buten-3-one
121488-67-3

(E)-1-(3-Phenoxyphenyl)buten-3-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-3-(4-(benzyloxy)phenyl)-N-methoxy-N-methylacrylamide
134197-95-8

(E)-3-(4-(benzyloxy)phenyl)-N-methoxy-N-methylacrylamide

1-(4-benzyloxyphenyl)but-1-en-3-one
75676-91-4

1-(4-benzyloxyphenyl)but-1-en-3-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(E)-N-Methoxy-N-methyl-3-[4-(1-phenyl-ethoxy)-phenyl]-acrylamide
134197-93-6

(E)-N-Methoxy-N-methyl-3-[4-(1-phenyl-ethoxy)-phenyl]-acrylamide

(E)-4-[4-(1-Phenyl-ethoxy)-phenyl]-but-3-en-2-one
134197-92-5

(E)-4-[4-(1-Phenyl-ethoxy)-phenyl]-but-3-en-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-<(trimethylsilyl)methyl>-2-butenal
122421-16-3

2-<(trimethylsilyl)methyl>-2-butenal

(Z)-3-((trimethylsilyl)methyl)pent-3-en-2-ol
141023-16-7

(Z)-3-((trimethylsilyl)methyl)pent-3-en-2-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether for 0.333333h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

C26H24O2S
136964-79-9

C26H24O2S

11-methyl-12-phenyl-9,10-dihydro-9,10-etheno-anthracene
79979-60-5

11-methyl-12-phenyl-9,10-dihydro-9,10-etheno-anthracene

Conditions
ConditionsYield
palladium(II) acetylacetonate In tetrahydrofuran Heating;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

Methyl (1R,2S)-2-<2-(3-Isopropylphenyl)ethyl>-1-methyl-3-oxo-1-cyclohexanecarboxylate
134454-00-5

Methyl (1R,2S)-2-<2-(3-Isopropylphenyl)ethyl>-1-methyl-3-oxo-1-cyclohexanecarboxylate

Methyl (1R,2S,3R)-1,3-Dimethyl-1-hydroxy-2<2-(3-isopropylphenyl)-ethyl>cyclohexanecarboxylate
134365-17-6

Methyl (1R,2S,3R)-1,3-Dimethyl-1-hydroxy-2<2-(3-isopropylphenyl)-ethyl>cyclohexanecarboxylate

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 2h;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl
141807-44-5, 126613-06-7, 128544-05-8, 128575-34-8

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl

Conditions
ConditionsYield
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In diethyl ether at 0℃; for 24h; Reflux;100%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In diethyl ether at 20℃;99%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In diethyl ether at 20℃; for 1h; Substitution;99%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

8-oxabicyclo<3.2.1>oct-6-en-2-one
154811-20-8

8-oxabicyclo<3.2.1>oct-6-en-2-one

(1R,2R,5R)-2-Methyl-8-oxa-bicyclo[3.2.1]oct-6-en-2-ol

(1R,2R,5R)-2-Methyl-8-oxa-bicyclo[3.2.1]oct-6-en-2-ol

Conditions
ConditionsYield
In diethyl ether at 0℃;100%
In diethyl ether at 0℃;
pyridine-2-carbaldehyde
1121-60-4

pyridine-2-carbaldehyde

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Conditions
ConditionsYield
In diethyl ether at 0℃; for 2h;100%
In diethyl ether at 0 - 5℃; for 2h; Inert atmosphere;61%
Yield given;
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(3aS,5R,5aR,6aS,9aS,9bS,9cS)-5-Methoxy-1,1,8,8,9c-pentamethyl-decahydro-4,7,9-trioxa-cyclopenta[e]acenaphthylen-6-one
161659-30-9

(3aS,5R,5aR,6aS,9aS,9bS,9cS)-5-Methoxy-1,1,8,8,9c-pentamethyl-decahydro-4,7,9-trioxa-cyclopenta[e]acenaphthylen-6-one

1,2,3,3aβ,5aβ,6,6aα,9aα,9bα,9c-decahydro-6α-hydroxy-5β-methoxy-1,1,6β,8,8,9cβ-hexamethyl-5H-furo<4',3',2':4,5>naphtho<1,2-d><1,3>dioxolane
161659-31-0

1,2,3,3aβ,5aβ,6,6aα,9aα,9bα,9c-decahydro-6α-hydroxy-5β-methoxy-1,1,6β,8,8,9cβ-hexamethyl-5H-furo<4',3',2':4,5>naphtho<1,2-d><1,3>dioxolane

Conditions
ConditionsYield
In diethyl ether for 1h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

7-(4-chlorophenylthio)-6,7-dihydro-1-(phenylsulfonyl)-1H-indol-4(5H)-one
157396-11-7

7-(4-chlorophenylthio)-6,7-dihydro-1-(phenylsulfonyl)-1H-indol-4(5H)-one

1-Benzenesulfonyl-7-(4-chloro-phenylsulfanyl)-4-methyl-4,5,6,7-tetrahydro-1H-indol-4-ol
146564-05-8

1-Benzenesulfonyl-7-(4-chloro-phenylsulfanyl)-4-methyl-4,5,6,7-tetrahydro-1H-indol-4-ol

Conditions
ConditionsYield
In tetrahydrofuran for 4h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

Bis-(1-triisopropylsilanyl-1H-pyrrol-3-yl)-methanone
161227-56-1

Bis-(1-triisopropylsilanyl-1H-pyrrol-3-yl)-methanone

C28H50N2Si2
161227-57-2

C28H50N2Si2

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether for 2h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-Benzyl-6-methyl-1-phenyl-3,4-dihydro-isoquinolinium; iodide

2-Benzyl-6-methyl-1-phenyl-3,4-dihydro-isoquinolinium; iodide

2-benzyl-1,6-dimethyl-1-phenyl-1,2,3,4-tetrahydroisoquinoline
174784-47-5

2-benzyl-1,6-dimethyl-1-phenyl-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-Benzyl-1-cyclohexyl-3,4-dihydro-isoquinolinium; bromide

2-Benzyl-1-cyclohexyl-3,4-dihydro-isoquinolinium; bromide

2-benzyl-1-cyclohexyl-1-methyl-1,2,3,4-tetrahydroisoquinoline
126115-25-1

2-benzyl-1-cyclohexyl-1-methyl-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Ambient temperature;100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

(1S,2R,5S)-2-Benzyloxy-1,5-dimethyl-8-oxa-bicyclo[3.2.1]octan-6-one

(1S,2R,5S)-2-Benzyloxy-1,5-dimethyl-8-oxa-bicyclo[3.2.1]octan-6-one

(1R,2S,5R,6R)-2-Benzyloxy-1,5,6-trimethyl-8-oxa-bicyclo[3.2.1]octan-6-ol

(1R,2S,5R,6R)-2-Benzyloxy-1,5,6-trimethyl-8-oxa-bicyclo[3.2.1]octan-6-ol

Conditions
ConditionsYield
In diethyl ether100%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

N-(tert-butoxycarbonyl)-D-alanine methyl ester
91103-47-8

N-(tert-butoxycarbonyl)-D-alanine methyl ester

((R)-2-hydroxy-1,2-dimethyl-propyl)-carbamic acid tert-butyl ester
186466-64-8

((R)-2-hydroxy-1,2-dimethyl-propyl)-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: methylmagnesium bromide; N-(tert-butoxycarbonyl)-D-alanine methyl ester In tetrahydrofuran at 0 - 20℃; for 16h;
Stage #2: With water In tetrahydrofuran Cooling with ice;
100%
Stage #1: methylmagnesium bromide; N-(tert-butoxycarbonyl)-D-alanine methyl ester In tetrahydrofuran at 0 - 20℃; for 3h;
Stage #2: With water; ammonium chloride In tetrahydrofuran
99%
In tetrahydrofuran; diethyl ether at 0 - 25℃; for 2h;99%
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 75-16-1