cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

Base Information

Chemical Name:cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]
CAS No.:1240923-91-4
Molecular Formula:C₄₀H₄₀P₂PtSe
Molecular Weight:856.745
Hs Code.:

Synonyms:cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

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Chemical Property of cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

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Technology Process of cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

There total 1 articles about cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 34172-61-7
bis(tert-butyl) diselenide

: 87518-11-4
(bicyclo[2.2.1]hept-2-ene)bis(triphenylphosphine)platinum

: 1240923-91-4
cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

Guidance literature:: With NaBH₄; In tetrahydrofuran; under Ar; (t)BuSeSe(t)Bu in THF was added to suspn. of NaBH4 in THF at 0°C; stirring for 1 h at room temp., quenching with EtOH; a soln. of (t)BuSeH (0.81 mmol) was added to Pt-contg. compd. (0.82 mmol) in THF; stirring 3 h at room temp.; the solvent was removed under reduced pressure, the residue was dissolved in benzene; it was filtered through a pad of Celite and rinsed with benzene; the solvent was removed under reduced pressure, the solid was washed 3 times with ether; elem. anal.;
DOI:10.1021/ic1011742

Reference yield: 30.0%

: 1240923-91-4
cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

: 1240923-97-0
cis-[Pt2H2(μ-1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

: 1240924-02-0
cis-[Pt2H(1,1-dimethylethaneselenol-H)(μ-1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

Guidance literature:: In toluene; byproducts: PPh3; under Ar; a soln. of Pt-contg. compd. (0.036 mmol) in toluene was heatedat 80°C for 3 h; the solvent was removed under reduced pressure; silica gel chromy. (hexane/CH2Cl2 = 1:1); elem. anal.;
DOI:10.1021/ic1011742

Reference yield:

: 1240923-91-4
cis-[PtH(1,1-dimethylethaneselenol-H)(triphenylphosphine)2]

: 922-67-8
propynoic acid methyl ester

: 867300-59-2
(η-methylpropiolate)bis(triphenylphosphine)platinum

Guidance literature:: In benzene; byproducts: E-C2H2((t)BuSe)(CO2Me), Z-C2H2((t)BuSe)(CO2Me); under Ar; to a soln. of Pt-contg. compd. (0.11 mol) in benzene was addedmethyl propiolate (0.11 mmol); the mixt. was heated at 60°C for 5 h; the solvent was removed in vac.;
DOI:10.1021/ic1011742