C₂₉H₄₁NO₅Si

Base Information

Chemical Name:C₂₉H₄₁NO₅Si
CAS No.:191787-66-3
Molecular Formula:C₂₉H₄₁NO₅Si
Molecular Weight:511.734
Hs Code.:

C<sub>29</sub>H<sub>41</sub>NO<sub>5</sub>Si

Synonyms:C₂₉H₄₁NO₅Si

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Chemical Property of C₂₉H₄₁NO₅Si

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Technology Process of C₂₉H₄₁NO₅Si

There total 19 articles about C₂₉H₄₁NO₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 186809-25-6
C₃₆H₄₇NO₇SSi

: 191787-66-3
C₂₉H₄₁NO₅Si

Guidance literature:: With sodium naphthalenide; In 1,2-dimethoxyethane; at -78 ℃;
DOI:10.1021/ja970839n

Reference yield:

: 191787-58-3
(3S,4R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-oct-7-ynenitrile

: 191787-66-3
C₂₉H₄₁NO₅Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: LiAlH₄; Darvon alcohol / -78 °C

2.1: 98 percent / DMAP; triethylamine / CH₂Cl₂ / 0 - 20 °C

3.1: lithium / tetrahydrofuran / 0 - 20 °C

3.2: CuCN / tetrahydrofuran / 0.5 h / 0 °C

3.3: 84 percent / tetrahydrofuran / -96 - -90 °C

4.1: 78 percent / diisobutylaluminum hydride / toluene; hexane / -78 - 0 °C

5.1: 1,3,5-trimethyl-benzene / Heating

6.1: tetrabutylammonium fluoride / tetrahydrofuran; 1,3,5-trimethyl-benzene / 1 h / 0 °C

7.1: 93 percent / H₂; quinoline / Lindlar catalyst / methanol / 19 h / 20 °C

8.1: 74 percent / trimethylbenzylammonium chloride; triethylamine / P(PPh₃)4 / acetonitrile / 48 h / 120 °C

9.1: 92 percent / DMAP; pyridine / 20 h / 100 °C

10.1: 1-pyrrolylborane

11.1: 96 percent / sodium naphthalenide / 1,2-dimethoxy-ethane / -78 °C

With pyridine; quinoline; dmap; lithium aluminium tetrahydride; 1-pyrrolylborane; Darvon alcohol; tetrabutyl ammonium fluoride; hydrogen; benzyltrimethylammonium chloride; lithium; sodium naphthalenide; diisobutylaluminium hydride; triethylamine; Lindlar's catalyst; P(PPh₃)4; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; toluene; acetonitrile; 1,3,5-trimethyl-benzene; 1.1: Reduction / 2.1: Acetylation / 3.1: Metallation / 3.2: transmetalation / 3.3: silacupration / 4.1: Reduction / 5.1: imino ene cyclization / 6.1: desylilation / 7.1: Reduction / 8.1: Heck cyclization / 9.1: Tosylation / 10.1: hydroboration / 11.1: detosylation;
DOI:10.1021/ja970839n

Reference yield:

: (3S,4R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-oct-7-ynenitrile

: 191787-66-3
C₂₉H₄₁NO₅Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: 82 percent / Jones reagent / acetone / 0 °C

2.1: LiAlH₄; Darvon alcohol / -78 °C

3.1: 98 percent / DMAP; triethylamine / CH₂Cl₂ / 0 - 20 °C

4.1: lithium / tetrahydrofuran / 0 - 20 °C

4.2: CuCN / tetrahydrofuran / 0.5 h / 0 °C

4.3: 84 percent / tetrahydrofuran / -96 - -90 °C

5.1: 78 percent / diisobutylaluminum hydride / toluene; hexane / -78 - 0 °C

6.1: 1,3,5-trimethyl-benzene / Heating

7.1: tetrabutylammonium fluoride / tetrahydrofuran; 1,3,5-trimethyl-benzene / 1 h / 0 °C

8.1: 93 percent / H₂; quinoline / Lindlar catalyst / methanol / 19 h / 20 °C

9.1: 74 percent / trimethylbenzylammonium chloride; triethylamine / P(PPh₃)4 / acetonitrile / 48 h / 120 °C

10.1: 92 percent / DMAP; pyridine / 20 h / 100 °C

11.1: 1-pyrrolylborane

12.1: 96 percent / sodium naphthalenide / 1,2-dimethoxy-ethane / -78 °C

With pyridine; quinoline; dmap; lithium aluminium tetrahydride; jones reagent; 1-pyrrolylborane; Darvon alcohol; tetrabutyl ammonium fluoride; hydrogen; benzyltrimethylammonium chloride; lithium; sodium naphthalenide; diisobutylaluminium hydride; triethylamine; Lindlar's catalyst; P(PPh₃)4; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; acetone; toluene; acetonitrile; 1,3,5-trimethyl-benzene; 1.1: Oxidation / 2.1: Reduction / 3.1: Acetylation / 4.1: Metallation / 4.2: transmetalation / 4.3: silacupration / 5.1: Reduction / 6.1: imino ene cyclization / 7.1: desylilation / 8.1: Reduction / 9.1: Heck cyclization / 10.1: Tosylation / 11.1: hydroboration / 12.1: detosylation;
DOI:10.1021/ja970839n