7-Bromomethylfluoranthene

Base Information

Chemical Name:7-Bromomethylfluoranthene
CAS No.:77061-07-5
Molecular Formula:C₁₇H₁₁Br
Molecular Weight:295.178
Hs Code.:2903999090
UNII:VCK2CJ2GZ5
DSSTox Substance ID:DTXSID20227858
Wikidata:Q83107696
Mol file:77061-07-5.mol

Synonyms:7-Bromomethylfluoranthene;77061-07-5;VCK2CJ2GZ5;7-(bromomethyl)fluoranthene;CCRIS 5206;UNII-VCK2CJ2GZ5;SCHEMBL16201010;DTXSID20227858;FLUORANTHENE, 7-(BROMOMETHYL)-

Suppliers and Price of 7-Bromomethylfluoranthene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
7-BROMOMETHYLFLUORANTHENE 95.00%
5MG
$ 503.01

Total 1 raw suppliers

Chemical Property of 7-Bromomethylfluoranthene

Chemical Property:

Vapor Pressure:1.22E-07mmHg at 25°C
Melting Point:105-107 °C
Boiling Point:443.3°C at 760 mmHg
Flash Point:225.5°C
PSA：0.00000
Density:1.541g/cm³
LogP:5.38210
XLogP3:5.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:294.00441
Heavy Atom Count:18
Complexity:313

Purity/Quality:: 7-BROMOMETHYLFLUORANTHENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC2=C3C(=C1)C4=CC=CC(=C4C3=CC=C2)CBr

Technology Process of 7-Bromomethylfluoranthene

There total 2 articles about 7-Bromomethylfluoranthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 23339-05-1
7-methylfluoranthene

: 77061-07-5
7-(bromomethyl)fluoranthene

Guidance literature:: With N-Bromosuccinimide; Perbenzoic acid; In tetrachloromethane; for 3h; Heating;
DOI:10.1021/jo00325a028

Reference yield:

: 77096-72-1
7-methyl-6b,7,10,10a-tetrahydrofluoranthene

: 77061-07-5
7-(bromomethyl)fluoranthene

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / DDQ / xylene / 5 h / Heating

2: 80 percent / N-bromosuccinimide, benzoyl peroxide / CCl₄ / 3 h / Heating

With N-Bromosuccinimide; Perbenzoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrachloromethane; xylene;
DOI:10.1021/jo00325a028

Reference yield:

: 77061-07-5
7-(bromomethyl)fluoranthene

: 77061-16-6
12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene

Guidance literature:: Multi-step reaction with 10 steps

1: 78 percent / diethyl ether / 30 h / Heating

2: 1.) diborane, 2.) 30percent H₂O₂ / 1.) THF, from 0 deg C to room temp., 8 h, 2.) reflux, 1 h

3: pyridinium chlorochromate / CH₂Cl₂ / 1 h / 20 °C

4: 85 percent / AgNO₃, 1.5 KOH / ethanol; H₂O / 2 h

5: SOCl₂ / benzene / 3 h / Heating

6: 1.) AlCl₃ / CS₂ / 1.) 0 deg C, 2.) reflux, 10 min

7: LiAlH₄ / tetrahydrofuran / 0.33 h / 20 °C

8: 60 percent / conc. H₂SO₄ / acetic acid / 3 h / 60 °C

9: 62 percent / 1.) I₂ / benzene / 1.) reflux, 2.) reflux, 2.5 h

10: 30 percent / N-bromsuccinimide, α,α'-azobis(isobutyronitrile) / CCl4 / 2 h / Heating

With potassium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; aluminium trichloride; thionyl chloride; sulfuric acid; azobisisobutyronitrile; dihydrogen peroxide; iodine; silver nitrate; pyridinium chlorochromate; diborane; In tetrahydrofuran; carbon disulfide; tetrachloromethane; diethyl ether; ethanol; dichloromethane; water; acetic acid; benzene;
DOI:10.1021/jo00325a028