23339-05-1

Usage

InChI:InChI=1/C17H12/c1-11-5-2-8-13-14-9-3-6-12-7-4-10-15(16(11)13)17(12)14/h2-10H,1H3

Upstream product

• 857007-70-6 3-methyl-2-(naphthalen-1-yl)aniline 
• 7664-93-9 sulfuric acid 
• 90-14-2 1-Iodonaphthalene 
• 713124-61-9 10-methyl-fluoranthene-7-carboxylic acid ethyl ester 
• 2963-87-3 trans-1,2-acenaphthalenediol 
• 82-86-0 acenaphthene quinone 
• 33718-15-9 1-bromo-8-fluoronaphthalene 
• 16419-60-6 2-Methylphenylboronic acid 
• 569674-03-9 1-(2-methyl-6-nitrophenyl)naphthalene 
• 41085-43-2 2-bromo-3-nitrotoluene 
• 77096-72-1 7-methyl-6b,7,10,10a-tetrahydrofluoranthene 

Downstream Products

• 77061-07-5 7-(bromomethyl)fluoranthene 
• 76479-14-6 trans-9,10-dihydro-9,10-dihydroxybenzofluoranthene 
• 77061-17-7 trans-9,10-bis(benzoyloxy)-9,10-dihydrobenzofluoranthene 
• 77061-15-5 trans-9,10-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene 
• 77061-16-6 12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene 

Relevant academic research and scientific papers

Solid-state construction of zigzag periphery: Via intramolecular C-H insertion induced by alumina-mediated C-F activation

Caryl-F bond activation has become an important and quickly developing method for construction of carbon-based materials. We report that alumina-mediated C-F bond activation (AmCFA) enables construction of PAHs with zigzag periphery. This method includes

Benzannulation via ruthenium-catalyzed diol-diene [4+2] cycloaddition: One- and two-directional syntheses of fluoranthenes and acenes

A new benzannulation protocol is described and applied to the synthesis of polycyclic aromatic hydrocarbons. Ruthenium(0)-catalyzed diol-diene [4+2] cycloaddition delivers cyclohex-1-ene-4,5-diols, which are subject to aromatization upon dehydration or Nicholas diol deoxydehydration. Employing diol and tetraol reactants, benzannulation can be conducted efficiently in one- and two-directional modes, respectively, as illustrated in the construction of substituted fluoranthenes and acenes.

Synthesis of Dihydro Diols as Potential Proximate Carcinogens of Benzofluoranthenes

Dihydro diols which are potential proximate carcinogens of the environmental agents benzofluoranthene (1), benzofluoranthene (2), and benzofluoranthene (3) were synthesized.The dihydro diols synthesized were trans-9,10-dihydro-9,10-dihydrobenzob