C₂₃H₃₅NO₂S₂Si

Base Information

Chemical Name:C₂₃H₃₅NO₂S₂Si
CAS No.:1325710-90-4
Molecular Formula:C₂₃H₃₅NO₂S₂Si
Molecular Weight:449.754
Hs Code.:

C<sub>23</sub>H<sub>35</sub>NO<sub>2</sub>S<sub>2</sub>Si

Synonyms:C₂₃H₃₅NO₂S₂Si

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Chemical Property of C₂₃H₃₅NO₂S₂Si

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Technology Process of C₂₃H₃₅NO₂S₂Si

There total 2 articles about C₂₃H₃₅NO₂S₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1325710-89-1
(2R,3S)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2-methylhex-5-en-1-one

: 69739-34-0
t-butyldimethylsiyl triflate

: 1325710-90-4
C₂₃H₃₅NO₂S₂Si

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -70 - 0 ℃; for 0.833333h;
DOI:10.1021/ol201920j

Reference yield:

: 863324-53-2
(R)-1-(4-benzyl-2-thioxothiazolidin-3-yl)propan-1-one

: 1325710-90-4
C₂₃H₃₅NO₂S₂Si

Guidance literature:: Multi-step reaction with 2 steps

1: 1-methyl-pyrrolidin-2-one; titanium tetrachloride; (-)-sparteine / dichloromethane / 4.5 h / -70 - 0 °C

2: 2,6-dimethylpyridine / dichloromethane / 0.83 h / -70 - 0 °C

With 2,6-dimethylpyridine; 1-methyl-pyrrolidin-2-one; titanium tetrachloride; (-)-sparteine; In dichloromethane;
DOI:10.1021/ol201920j

Reference yield:

: 1325710-90-4
C₂₃H₃₅NO₂S₂Si

: 1325710-75-5
C₄₂H₆₆O₈Si

Guidance literature:: Multi-step reaction with 15 steps

1.1: diisobutylaluminium hydride / hexane; dichloromethane / -78 °C / Inert atmosphere

2.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 12 h / 20 °C / Inert atmosphere

3.1: methanol; L-diisopinocampheylborane / diethyl ether / 1 h / 0 - 20 °C

3.2: 3 h / -70 °C

4.1: potassium carbonate / methanol

5.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate / dichloromethane / -70 - 0 °C / Molecular sieve

6.1: 1H-imidazole; dmap / dichloromethane / 2 h / 20 °C

7.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1.25 h / -70 °C

7.2: 2 h / -70 - 20 °C

8.1: dimethyl zinc(II); tert.-butyl lithium / tetrahydrofuran; n-heptane; pentane / 1.75 h / -70 °C / Inert atmosphere

8.2: 3 h / -70 °C / Inert atmosphere

9.1: pyridinium p-toluenesulfonate / tetrahydrofuran; methanol

10.1: pyridinium p-toluenesulfonate

11.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 4 h / Reflux; Inert atmosphere

12.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 0 °C

13.1: quinoline; hydrogen / hexane; ethyl acetate / 1.5 h

14.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.25 h / 0 °C

15.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 °C

15.2: 2 h / 0 °C

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; quinoline; titanium(IV) isopropylate; methanol; tert.-butylhydroperoxide; dmap; oxalyl dichloride; diethyl (2R,3R)-tartrate; tetrabutyl ammonium fluoride; hydrogen; dimethyl zinc(II); tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; L-diisopinocampheylborane; In tetrahydrofuran; methanol; diethyl ether; hexane; n-heptane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; mineral oil; pentane; 5.1: Sharpless epoxidation / 7.1: Swern oxidation / 7.2: Swern oxidation / 8.2: Felkin-Anh addition;
DOI:10.1021/ol201920j